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Chemical Reaction Engineering: Asynchronous Video Series

This document discusses reaction stoichiometry in batch systems. It introduces the concept of a batch stoichiometric table that lists the initial and remaining amounts of species in a reaction. The table includes reaction components, products, and inerts. It notes that for constant volume batch reactors where reactions occur in liquid or rigid gas phases, concentrations can be related to the fraction of A reacted using the stoichiometric ratios and initial amounts of species. The document emphasizes that stoichiometry is needed to determine reaction rates as a function of conversion and properly size continuous flow reactors.

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ZAHID HUSSAIN
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© © All Rights Reserved
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Download as PPT, PDF, TXT or read online on Scribd
47 views

Chemical Reaction Engineering: Asynchronous Video Series

This document discusses reaction stoichiometry in batch systems. It introduces the concept of a batch stoichiometric table that lists the initial and remaining amounts of species in a reaction. The table includes reaction components, products, and inerts. It notes that for constant volume batch reactors where reactions occur in liquid or rigid gas phases, concentrations can be related to the fraction of A reacted using the stoichiometric ratios and initial amounts of species. The document emphasizes that stoichiometry is needed to determine reaction rates as a function of conversion and properly size continuous flow reactors.

Uploaded by

ZAHID HUSSAIN
Copyright
© © All Rights Reserved
Available Formats
Download as PPT, PDF, TXT or read online on Scribd
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Chemical Reaction Engineering

Asynchronous Video Series

Chapter 3, Part 2:
Reaction Stoichiometry: Batch

H. Scott Fogler, Ph.D.


Why Stoichiometry?
• If we have FA 0
− rA

• Then we can size a number of CSTR and PFR reaction systems

• To find -rA= f(X)


1) Need the rate law, -rA=f(CA, CB) !!
2) Need the reaction stoichiometry, CA=CA0(1-X) [Liquid Phase]
Batch Stoichiometric Table

Species Symbol Initial Change Remaining


A A

________ ____________
Batch Stoichiometric Table

Species Symbol Initial Change Remaining


A A

B B ΘB =
N B0
N A0

________ ____________
Batch Stoichiometric Table

Species Symbol Initial Change Remaining


A A

B B ΘB =
N B0
N A0

C C

________ ____________
Batch Stoichiometric Table

Species Symbol Initial Change Remaining


A A

B B ΘB =
N B0
N A0

C C

D D

________ ____________
Batch Stoichiometric Table

Species Symbol Initial Change Remaining


A A

B B ΘB =
N B0
N A0

C C

D D
Inert I -------
________ ____________
Batch Stoichiometric Table

Species Symbol Initial Change Remaining


A A

B B ΘB =
N B0
N A0

C C

D D
Inert I -------
________ ____________
Batch Stoichiometric Table

Species Symbol Initial Change Remaining


A A

B B ΘB =
N B0
N A0

C C

D D
Inert I -------
________ ____________

where and
Concentration: Batch Systems
Constant Volume Batch:
Concentration: Batch Systems
Constant Volume Batch:

Note:              if the reaction occurs in the liquid phase


                                               or 
     if a gas phase reaction occurs in a rigid (e.g., steel) batch reactor
Then
Concentration: Batch Systems
Constant Volume Batch:

Note:              if the reaction occurs in the liquid phase


                                               or 
     if a gas phase reaction occurs in a rigid (e.g., steel) batch reactor
Then

etc.
Concentration: Batch Systems
Constant Volume Batch:

Note:              if the reaction occurs in the liquid phase


                                               or 
     if a gas phase reaction occurs in a rigid (e.g., steel) batch reactor
Then

etc.

If then

And we have –rA=f(X)

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