Material Science Unit-2 Solutions
Material Science Unit-2 Solutions
ENGINEERING
DISCOVER . LEARN .
EMPOWER
Material Science
22AST-216
Academic Session : JUL- DEC 2023
Semester : III
Mr. UMA SHANKER
Faculty of Aerospace Department,
Chandigarh University
[email protected]
Primary Goals
3
COURSE PRE-REQUISITES
4
COURSE OBJECTIVE
5
Lect-22-B
SYLLABUS
UNIT-2
3. Electronic Materials: Fermi energy and Fermi–Dirac distribution
function –Variation of Fermi level with temperature in intrinsic and
extrinsic semiconductors – Hall Effect – Dilute Magnetic
Semiconductors (DMS) and their applications.
6
Ques-1 To high-purity silicon is added 1023 m-3 arsenic atoms.
(a) Demonstrate whether it is n-type or p-type
(b) Calculate the room-temperature electrical conductivity of this material.
(c) Determine the conductivity at 100°C (373 K)
Solution-
(a)Arsenic is a group VA element and therefore acts as a donor in silicon and it
means that this material is n-type. (Ans)
(b)At room temperature (298K) i.e. the extrinsic temperature region which
shows all of the arsenic atoms have donated electrons (n=10^23 m^-3). Since
this material is extrinsic n-type thus it is necessary to determine the electron
mobility for a donor concentration of 10^23 m^-3.
At 10^23 m^-3, μe =0.07 m^2/V-s
σ = n |e| μe = (10^23) x (1.6x10^-19) x (0.07) = 1120 (Ω-m)^-1 (Ans)
Conti…
( c) To solve for the conductivity of this material at 373 K and electron mobility at
this temperature.
For 10^23 m^-3 at 373K, μe= 0.04 m^2/V-s
Therefore,
Electrical Conductivity,
σ = n |e| μe = (10^23) x (1.6x10^-19) x (0.04) = 640 (Ω-m)^-1 (Ans)
Solu- As an element when added to silicon then it p-type lie one group to the left of
silicon in the periodic table and it includes the group IIIA elements i.e. Boron,
Aluminum, Gallium and Indium.
Since this material is extrinsic and p-type (p >> n), therefore the electrical
conductivity is a function of both hole concentration and hole mobility.
Conti…
It is also assumed that at room temperature, all the acceptor dopant atoms have
accepted electrons to form holes (extrinsic region) i.e. the number of holes is
approximately equal to the number of acceptor impurities Na.
μh is dependent on impurity content. This problem has been solved
through trail and error.
Assume an impurity concentration, then compute the conductivity using
this value and corresponding hole mobility. Then on the basis of this result,
repeat the process, assuming another impurity concentration.
Let-
Na=10^22 m^-3 (a p value) and this concentration, the hole mobility = 0.04
m^2/V-s
Therefore, the conductivity,
σ = p |e| μh = (10^22) x (1.6x10^-19) x (0.04) = 64 (Ω-m)^-1 (Ans)
Conti…
On decreasing the impurity content an order of magnitude to 10^21 m^-3 results in
only slight increase of μh = 0.045 m^2/V-s.
Thus the resulting conductivity,
σ = p |e| μh = (10^21) x (1.6x10^-19) x (0.045) = 7.2 (Ω-m)^-1 (Ans)
A conductivity of 50 (Ω-m)^-1 is achieved when Na = p = 8x10^21 m^-3
And at this Na value, μh remains approximately 0.04 m^2/V-s
• FERROELECTRICITY
• PIEZOELECTRICITY
1. Palanisamy P.K., Physics II, Material Science for ECE, Scitech Publications (India) Pvt Ltd., 2006.
2. Safa O. Kasap, Principles of Electronic materials and devices, McGraw Hill Publishers, 3rd Edition,
2006.
REFERENCES:
1. Arumugam.M, Physics II, Material Science for ECE, Anuradha Publishers, 5th Edition, 2005.
2. Jacob Millman, Christos C.Halkais, Electronic Devices and Circuits, Tata McGraw-Hill, New Delhi,
1991.
3. Charles Kittel, Introduction to solid state physics, 7th Edition, John Wiley & sons (ASIA) Pvt. Ltd.
1. Sze. S.M., Semiconductor Devices – Physics and Technology, 2nd edn. John Wiley, 2002.