The document discusses different methods of extractive metallurgy including pyrometallurgy, hydrometallurgy, and electrometallurgy. Pyrometallurgy involves applying heat to extract metals and includes processes like roasting, calcination, and smelting. Hydrometallurgy uses methods like leaching and flotation. Electrometallurgy uses electrolysis.
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The document discusses different methods of extractive metallurgy including pyrometallurgy, hydrometallurgy, and electrometallurgy. Pyrometallurgy involves applying heat to extract metals and includes processes like roasting, calcination, and smelting. Hydrometallurgy uses methods like leaching and flotation. Electrometallurgy uses electrolysis.
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Extractive Metallurgy
Dr. Wafaa K. mahmood
INTRODUCTION: -
It deals with extraction of metals from ore refining &
alloying. There are mainly three routes by which metals are extracted from ore.
1. Pyrometallurgy: - It involves application of heat to
reduce metal from ore. Most commonly used methods of pyrometallurgy are Roasting, Calcinations,
2. Hydrometallurgy: - It involves application of
methods such as selective leaching, froth floatation to extract metal.
3. Electrometallurgy: - It involves application of
electrolysis process to obtain metal from ore. Pyrometallurgy Pyrometallurgy Pyrometallurg deals with the extraction of mineralsyfrom ore by treating them with heat.
Raosting Calcunation Smelting
Pyrometallurgy deals with chemical reactions at high temperatures. These are reactions that take place at temperatures from 100°C up to 3000°C or more. Pyrometallurgy or fire metallurgy is the most important of the extraction processes and it is the oldest division of metallurgy. Practically all iron and steel, lead, and tin, most copper, and a small proportion of zinc, etc. are won from their ores and concentrates by pyrometallurgical methods. Pyrometallurgical reactions involve a number of different solids, liquids and gases and, take place in a variety of furnaces, converters, roasters and other devices. The most important pyrometallurgical extraction processes are as follows: 1. Roasting – agglomeration – calcination and drying (these are pretreatment processes that are pyrometallurgical in nature.)
2. Smelting - Matte smelting (Cu and Ni, etc.)
- Smelting for metal (Fe, Pb, etc.)
3. Converting (Cu, Ni, etc.)
4. Reduction of oxides, etc. (Direct reduction of iron ore, zinc ore, etc.) 5. Refining (Cu, Pb, etc.) 1. Smelting Smelting is mainly a process of melting and separation of the charge into two immiscible liquid layers, i.e. a liquid slag and a liquid matte or a liquid metal. There are two types of smelting: 1. Smelting for matte 2. Smelting for metal. Matte can be defined as molten mixture of sulphides of heavy metals. Liquid slag is the siliceous or oxidized part of the concentrate. Matte smelting is done in one of the following furnaces: (Diagrams given below) Reverberatory furnace (for fine concentrates) Flash furnace (for fine concentrates) Blast furnace (for lumpy ore or agglomerated concentrates) Electric furnace (for fine concentrates) Matte smelting is therefore a pyrometallurgical concentrating stage in the overall extraction of a metal from its sulphides. 2. Converting Reduction of Metal Oxides Refining Distillation