EVS Chapter 2
EVS Chapter 2
AND SUSTAINABILITY
By:
Dr. A. RAVIKRISHNAN,
M.Sc., M.Phil., M.Ed., Ph.D., MISTE., MILCS.,
Asst.Prof of Chemistry.
Environmental Pollution
1.1 Introduction
Examples
Industry, automobiles, thermal power plants, farming, nuclear
reactors, generate different types of pollutants causing pollution to air,
water bodies and land.
2.1.1 Types of Pollutants
1. Biodegradable pollutants:
Biodegradable pollutants decompose rapidly by natural processes.
2. Non-degradable pollutants:
Non-degradable pollutants do not decompose (or) decompose
slowly in the environment.
The slowly decomposed materials are more dangerous because it is
more difficult to remove them.
Definition
Air pollution may be defined as, “the presence of one (or) more
contaminants like dust, smoke, mist and odour in the atmosphere
which are injurious to human beings, plants and animals.”
Constituents %
Nitrogen 78
Oxygen 21
CO 2 0.037
1. Natural sources
Examples:
Volcanic eruptions, forest fires, biological decay, pollen grains,
marshes, radioactive materials etc.
Description
It is a colourless, odourless gas that is poisonous to air-breathing
animals.
It is formed during the incomplete combustion of carbon
containing fuels.
2C + O 2 −−−−−> 2CO
Environmental Effects
It increases the globe temperature.
2.Nitrogen dioxide ( NO 2)
Description
It is a reddish-brown irritating gas that gives photochemical smog.
In the atmosphere it can be converted into nitric acid ( HNO 3 ).
Health Effects
Lung irritation and damage.
Environmental Effects
Acid deposition of HNO 3 can damage trees, soils and aquatic
life in lakes, HNO 3 can corrode metals and eat away stone on
buildings, statues and monuments.
Health Effects
Breathing problems for healthy people.
Environmental Effects
Reduce visibility, acid deposition of H 2SO 4 can damage trees,
soils and aquatic life in lakes.
4. Suspended Particulate matter (SPM)
Description
It includes variety of particles and droplets (aerosols).
They can be suspended in atmosphere for short periods to long
periods.
Health Effects
Nose and throat irritation, lung damage, bronchitis, asthma,
reproductive problems and cancer.
Environmental Effects
Reduces visibility, acid deposition and H SO 4 droplets can
2
damage trees, soils and aquatic life in lakes.
4. Ozone (O )
3
Description
Highly reactive irritating gas with an unpleasant odour that
forms in the troposphere.
It is a major component of photochemical smog.
Environmental Effect
Moderates the climate.
6. Photochemical smog
Description
The brownish smoke like appearance that frequently forms on clear,
sunny days over large cities with significant amounts of automobile
traffic.
Sources (causes)
It is mainly due to chemical reactions among nitrogen oxides and
hydrocarbon by sunlight.
Health Effects
Breathing problems, cough, eye, nose and throat irritation, heart
diseases, reduces resistance to colds and pneumonia.
Environmental Effects
Ozone can damage plants and trees. Smog can reduce visibility.
7. Lead (pb)
Description
Solid toxic metal and its compounds, emitted into the atmosphere
as particulate matter.
Health Effects
Accumulates in the body, brain and other nervous system damage
and mental retardation (especially in children); digestive and other
health problems, some
lead-containing chemicals cause cancer in test animals.
Environmental Effect
Can harm wild life.
8. Hydrocarbons ( aromatic and aliphatic)
Description
Hydrocarbons especially lower hydrocarbons get accumulated
due to the decay of vegetable matter.
Health Effects
Carcinogenic.
Environmental effect
It produces an oily film on the surface and do not as such causes
a serious problem until they react to form secondary pollutants.
Ethylene causes plant damage even at low concentrations.
9. Chromium (Cr)
Description
It is a solid toxic metal, emitted into the atmosphere as
particulate matter.
Health effects
Perforation of nasal septum, chrome holes, gastro intestinal
ulcer, central nervous system disease and cancer.
2.2.4 Control (or) Preventive Measures of air pollution
The atmosphere has several built-in self cleaning processes such as
dispersion, gravitational settling, flocculation, absorption, rain washout
and so on, to cleanse the atmosphere.
1.Source control
Since we know the substances that causes air pollution, the first
approach to its control will be through source reduction.
The four figures (fig 2.1) are commonly used control methods for
removing particulates from the exhaust gases of electric power and
industrial plants.
All these methods retain hazardous materials that must be disposed
of safely.
The wet scrubber can also reduce sulphurdioxide emissions.
Definition
Water pollution may be defined as, “the alteration in physical,
chemical and biological characteristics of water which may cause
harmful effects on humans and aquatic life.”
Effects
Variety of diseases.
Effects
Large populations of bacteria decomposing these wastes can degrade
water quality by depleting water of dissolved oxygen.
This causes fish and other forms of oxygen-consuming aquatic life to
die.
3. Inorganic Chemical
Example: Water soluble inorganic chemicals.
acids,
compounds of toxic metals such as lead (Pb), arsenic (As) and
selenium (Se) and
salts such as NaCl in ocean water and fluorides (F−) found in
some soils.
Human Sources (causes)
Surface runoff, industrial effluents and household cleansers
Effects
Can make fresh water unusable for drinking (or) irrigation.
Causes skin cancers and neck damage.
Damage the nervous system, liver and kidneys.
Harm fish and other aquatic life.
Lower crop yields.
Accelerates corrosion of metals exposed to such water.
4. Organic Chemical
Effects
Can threaten human health by causing nervous system
damage and some cancers.
Harm fish and wild life.
5. Plant Nutrients
-
Examples Water-soluble compounds containing nitrate ( NO 3 ),
phosphate (PO 3-
4 ) and ammonium (NH +
4 ) ions.
6. Sediment
Examples Soil, silt, etc.,
Effects
Can reduce photosynthesis and cloud water.
Disrupt aquatic food webs.
Carry pesticides, bacteria, and other harmful substances.
Settle out and destroy feeding and spawning rounds of fish.
Clog and fill lakes, artificial reservoirs, stream channels and
harbours.
7. Radioactive Materials
Examples Radioactive isotopes of iodine, radon, uranium, cesium,
and thorium.
Effects
Genetic mutations, birth defects, and certain cancers.
8. Heat (Thermal Pollution)
Example Excessive heat
Effects
Lowers dissolved oxygen levels and makes aquatic organisms
more vulnerable to disease, parasites and toxic chemicals.
When a power plant first opens (or) shuts down for repair, fish and
other organisms adapted to a particular temperature range can be
killed by the abrupt change in water temperature known as thermal
shock.
9. Point and Non- point sources of water pollution
(i) Point Sources
Point sources are discharged pollutants at specific locations
through pipes, ditches (or) sewers into bodies of surface water.
Significance of DO
DO is vital for the support of fish and other aquatic life in river
water.
It determines whether the biological changes are brought about
by aerobic (or) anaerobic micro-organisms.
DO determinations serve as the means of control of river
pollution.
A minimum level of DO (4 mg/lit) must be maintained in rivers
so as to support the aquatic life in a healthy condition.
Thus, it is necessary to ensure that the treated water must have
atleast 4 mg/lit of DO before its disposal into river.
2. Biochemical Oxtgen Demand (BOD)
BOD is the amount of oxygen required for the biological
decomposition of organic matter present in the water.
Significance of BOD
It is an important indication of the amount of organic
matter present in the river water.
Significance of COD
It is carried out to determine the pollutional strength of river
water.
It is rapid process and takes only 3 hours.
Plants, trees and forests control pollution and they acts as natural air
conditioners.
Al ( SO ) + 6H O −−−−−> 2Al(OH) ↓ + 3H SO .
2 4 3 2 3 2 4
III Secondary (or) Biological Treatment
In this treatment, biodegradable organic impurities are removed by
aerobic bacteria.
It removes upto 90% of the oxygen demanding wastes.
This is done by trickling filter (or) activated sludge process.
V Disposal of sludge
This is the last stage in the sewage treatment.
Sludge formed from different steps can be disposed by
dumping into low-lying areas.
burning of sludge (incineration),
dumping into the sea,
using it as low grade fertilizers.
The flow sheet diagram of sewage treatment
Flow Chart
2.3.5 Specifications for Drinking Water
It should be cool.
1. Chlorides:
Although chlorides are not considered as harmful as such, their
concentrations over 250 mg/lit impart peculiar taste to water,
which is unacceptable for drinking purposes.
2. Sulphates:
When sulphates are present in excess amount in drinking water,
they may produce a cathartic effect on the people consuming such
water.
3. Nitrates:
Excessive concentrations of nitrates are undesirable especially
for infants.
The maximum contaminant level for nitrate is 10 mg/lit.
4. Fluorides:
5. Arsenic:
Arsenic is a toxic heavy metal even a very small dose can result in
severe poisoning.
Definition
Soil pollution is defined as, “the contamination of soil by human
and natural activities which may cause harmful effects on living
beings.”
Components %
Mineral matter (inorganic) 45
Organic matter 5
Soil water 25
Soil air 25
2.4.1 Types, effects and sources (causes) of soil pollution
Soil pollution mainly results from the following sources
Industrial wastes.
Urban wastes.
Agricultural practices.
Radioactive pollutants.
Biological agents.
1. Industrial wastes
Disposal of industrial wastes is the major problem for soil pollution.
Sources
The industrial pollutants are mainly discharged from the various
origins such as pulp and paper mills, chemical industries, oil refineries,
sugar factories, tanneries, textiles, steel, distilleries, fertilizers,
pesticides, coal and mineral mining industries, drugs, glass, cement,
petroleum and engineering industries etc.,
Effect
These pollutants affect and alter the chemical and biological
properties of soil.
As a result, hazardous chemicals can enter into human food chain
from the soil (or) water and disturb the biochemical process and finally
lead to serious effects on living organisms.
2. Urban wastes
Urban wastes comprises both commercial and domestic wastes
consisting of dried sludge of sewage.
All the urban solid wastes are commonly referred to as refuse.
3. Agricultural practices
Modern agricultural practices pollute the soil to a large extent.
Today with the advancing agro-technology, huge quantities of
fertilizers, pesticides, herbicides, weedicides are added to increase the
crop yield.
Apart from these farm wastes, manure, slurry, debris, soil erosion
containing mostly inorganic chemicals are reported to cause soil
pollution.
4. Radioactive pollutants
Radioactive substances resulting from explosions of nuclear dust
and radioactive wastes (produced by nuclear testing laboratories and
industries) penetrate the soil and accumulate there by creating land
pollution.
Examples
Radio nuclides of radium, thorium, uranium, isotopes of
potassium (K-40) and carbon (C-14) are very common in soil,
rock, water and air.
5. Biological agents
Soil gets large quantities of human, animal and bird’s excreta
which constitute the major source of land pollution by biological
agents.
Examples
Heavy application of manures and digested sludges could cause
serious damage to plants within a few years. Because the sludges are
containing more live viruses and viable intestinal worms.
In addition to these excreta, faulty sanitation, municipal garbage,
waste water and wrong methods of agricultural practices also induce
heavy soil pollution.
S. Industry Physico-chemical
No. characteristics
1. Pulp and Paper Suspended solids, high (or)
low pH, colour, fibres,
BOD, COD, high
temperature, fibres.
2. Rubber Chlorides, suspended and
Industry dissolved solids, variable
pH and high BOD.
3. Oil refineries Acids, alkalis, phenols, resinous materials
and petroleum oils.
4. Antibiotics Toxic organics and high acidity (or)
alkalinity.
5. Synthetic dru High suspended and dissolved
gs organic matter including vitamins.
6. Distillery Very high COD, low pH, high organic
matter, high suspended and dissolved solids
containing nitrogen, high potassium.
7. Organic che Toxic compounds, phenols, high acidity, al
mical industy kalinity.
Table 2.5 Major physico-chemical characteristics of untreated
wastes of Inorganic chemical industries in Soil
Example
(a) Trees may be planted on barren slopes.
(b) Contour cultivation and strip cropping may be practiced instead
of shifting cultivation.
(c) Terracing and building diversion channels may be undertaken.
Reducing deforestation and substituting chemical manures by
animal wastes would also help to arrest soil erosion in the long
term.
Maintaining soil productivity is vital and essential for
sustainable agriculture.
The surface so obtained then can be used for housing (or) sports
field.
3. Production of natural fertilizers
Excessive use of chemical fertilizers and insecticides should be
avoided. Biopesticides should be used in place of toxic chemical
pesticides.
Definition
Noise pollution is defined as, “the unwanted, unpleasant (or)
disagreeable sound that causes discomfort for all living beings.”
Industrial noise.
Transport noise.
Neighbourhood noise.
1. Industrial Noise
Highly intense sound (or) noise pollution is caused by many
machines.
Example In the steel industry, the workers near the heavy industrial
blowers are exposed to 112 dB for eight hours and suffer from the
occupational pollution.
2. Transport Noise
The main noise, comes from transport. It mainly includes road traffic
noise, rail traffic noise and air craft noise.
The number of road vehicles like motors, scooters, cars, motor
cycles, buses, trucks and particularly the diesel engine vehicles have
increased enormously in recent years.
That is why, this form of pollution is gaining importance, especially in
large and over crowded towns and cities.
According to experts, the noise level in most of the residential areas
in metropolitan cities is already hovering on the border line because of
vehicular noise pollution.
A survey conducted in metropolitan cities has shown that noise level
in Delhi, Bombay and Calcutta is as high as 90 dB.
Inhabitants of cities are subjected to this most annoying form of
transport noise which gradually deafen them.
3. Neighbourhood Noise
This type of noise includes disturbance from household gadgets
and community.
Common noise makers are musical instruments, TV, VCR,
radios, transistors, telephones, and loudspeakers etc.,
Ever since the industrial revolution, noise in environment has
been doubling every ten years.
3. Receptor control
This includes protection of the receiver by altering the work
schedule (or) provision of personal protection devices such as ear
plugs for operating noisy machinery.
The measure may include dissipation and deflection methods.
4. Oiling
Proper oiling will reduce the noise from the machines.
Silent zone 50 40
Residential zone 55 45
Commercial zone 65 55
Industrial zone 70 70
2.6 SOLID WASTE MANAGEMENT (OR) WASTE SHED
MANAGEMENT
Rapid population growth and urbanization in developing countries
have led to the generations of enormous quantities of solid wastes and
consequential environmental degradation.
Examples
(i) Nuclear power plants
It generates radioactive wastes.
(ii) Thermal power plants
It produces fly ash in large quantities.
(iii) Chemical industries
It produces large quantities of hazardous and toxic materials.
(iv) Other industries
Other industries produce, packing materials, rubbish, organic
wastes, acids, alkalis, scrap metals, rubber, plastic, paper, glass, wood,
oils, paints, dyes, etc.,
2.6.2 Effect of Solid Wastes (or) Effect of Improper Solid Waste
Management
Examples
(a) Old aluminium cans and glass bottles are melted and recast
into new cans and bottles.
(b) Preparation of cellulose insulation from paper.
(c) Preparation of fuel pellets from kitchen waste.
(d) Preparation of automobiles and construction materials from
steel cans.
1. Landfill
Solid wastes are placed in sanitary landfill system in alternate
layers of 80 cm thick refuse, covered with selected earth fill of 20 cm
thickness.
After two (or) three years, solid waste volume shrinks by 25-30%
and the land is used for parks, roads and small buildings.
The most common and cheapest method of waste disposal is
dumping in sanitary land-fills which is invariably employed in
Indian cities.
Land-fill structure is built either into the ground (or) on the
ground into which the waste is dumped.
The method involves spreading the solid waste on the ground,
compacting it and then covering it with soil at suitable intervals.
Advantages
It is simple and economical.
Segregation not required.
Landfilled areas can be reclaimed and used for other purposes.
Converts low-lying, marshy waste-land into useful areas.
Natural resources are returned to soil and recycled.
Disadvantages
A large area is required.
Since land is available away from town, transportation cost is
heavy.
Bad odours, if landfills are not properly managed.
The land filled areas will be the sources of mosquitoes and
flies and hence insecticides and pesticides are to be applied at
regular intervals.
Causes fire hazard due to the formation of methane in wet
weather.
The municipal solid waste is generally wet but has a very high
calorific value so it has to be dried up first before burning.
Disadvantages
Its capital and operating cost is high.
Needs skilled personnel.
Formation of smoke, dust and ashes needs further disposal, due
to which air pollution may be caused.
3. Composting
Advantages
When the manure is added to soil, it increases the water
retention and ion-exchange capacity of soil.
A number of industrial solid wastes can also be treated by this
method.
It can (manure) be sold thereby reducing the cost of
disposing of wastes.
Recycling - occurs.
Disadvantages
The non-consumables have to be disposed separately.
Use of compost has not yet caught up with farmers and hence
no assured market.
It is the waste that has potential threats to public health (or) the
environment.
Examples
Cleaning solvents (acids and bases).
Spent acids and bases.
Metal finishing wastes.
Painting wastes.
Sludges from air and water pollution control units.
Disinfectants and pesticides.
Definition
It is the collection, treatment and disposal of waste materials that
can cause substantial harm to human health (or) to the
environment.
Step 1: Analysis:
Physical and chemical properties of hazardous waste must be
analysed before collection and recovery of useful components.
Chemical method.
Thermal method.
Biological method.
Physical method.
1. Chemical method
It includes ion-exchange, precipitation, oxidation and reduction
and neutralization.
2. Thermal method
High temperature incineration
It not only can detoxify certain organic wastes but also can
destroy them.
Examples
Fluidized-bed incinerator, multiple hearth furnace, rotary kiln and
liquid-injection incinerator.
Problem
Hazardous-waste incineration is the source of air pollution.
3. Biological treatment
Bio-remediation
Microbes can also be used for stabilizing hazardous wastes on
previously contaminated sites.
Definition
e-waste describes discarded electrical (or) electronic devices.
e-wastes are considered dangerous because they contain
hazardous chemicals.
The hazardous content of e-waste pose a threat to human health
and environment.
Fig. 2.6 e-waste logo
2.8.1 Hazardous chemicals in e-wastes (or) Causes of e-wastes
Some of the hazardous chemicals present in some e-wastes are
Definition
Environmental protection is the practice of protecting the natural
environment by individuals, organizations and governments.
Objectives
Its objectives are
to conserve natural resources,
to conserve the existing natural environment,
to repair damage and reverse trends.
Due to the pressures of over consumption, population growth and
technology, the biophysical environment is being degraded. This has
been recognized and governments have begun placing restraints on
activities that cause environmental degradation.
Importance (or) Goal of environmental protection
To reduce air, water and land pollution.
The Act fixes the liability of the offence punishable under Act on
the person who is directly in charge. Whether he/she is the director
(or) Manager (or) Secretary (or) any other officer, unless he/she
proves that it was committed without his/her knowledge (or)
consent.
Use any new (or) altered outlet for the discharge of a sewage.
Wild life refers to all animals and plants that are not domesticated.
India has rich wildlife heritage.
It has 350 species of mammals, 1200 species of birds and about
20,000 known species of insects.
Some of them are listed as ‘endangered species’ in the Wildlife
(Protection) Act.
Wildlife is an integral part of our ecology and plays an essential
role in its functioning.
The wildlife is declining due to human actions, the wildlife
products - skins, furs, feathers, ivory etc., have decimated the
populations of many species. Wildlife populations are regularly
monitored and management strategies formulated to protect them.
Important features
The act covers the rights and non-rights of forest dwellers.