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DIFFUSION
• Diffusion is a process of adding impurities atoms froms a region with high
concentration semiconductor of low concentration. • The dopants or impurity atoms are added to the silicon (semiconductor material) changes its resistivity. • The process of diffusion is highly dependent on the temperature. • The depth and width of the impurities depend on the temperature range and the concentration. • The high doping concentration improves the conductivity of a metal. • For ex; the boron or indium diffusion on the n-type region forms a p-n junction • Most of these diffusion processes occur in two steps: • 1. Depositon(pre –deposition) :dopantsa(s)into the wafer surface • 2.Drive –in –oxidation:(spread) the dopants to desired path Pre-deposition: • pre-deposition is also known as constant source diffusion. • In this deposition the impurity concentration is maintained constant over the surface of the wafer. • Deposition (also called predeposition, dep, or predep) takes place in a tube furnace, with the wafers placed on a quartz “boat” in the flat zone of the tube. • A source of dopant atoms is located in the source cabinet and their vapors are transferred into the tube at a required concentration. • Liquid, gas, and solid dopant sources are used. • solid dopant source; • Liquid dopant source:
• Gaseous dopant source;
• There are mainly two types of physical mechanisms by which the impurities can diffuse into the lattice. They are I. Substitutional diffusion:
• interstitial diffusion: FICKS LAWS OF DIFFUSION
• The diffusion rate of impurities into semiconductor lattice depends on the
following: • Mechanism of diffusion • Temperature • Physical properties of impurity • The concentration gradient of impurities. • The behaviour of diffusion particles is governed by ficks law, which when solved for appropriate boundary conditions, gives rise to various dopant distributions ,called profiles which are approximated during actual diffusion procceses. The diffusion constant of a material is also referred to as ‘DIFFUSION COEFFFIENT’ or simply diffusivity. • It is expressed in units of length2/time,.the negative sign of the right side of the equation indicates that the impurities are flowing in the direction of lower concentration. DIFFUSION PROFILES
• Depending on boundary equations the ficks law has two types of
solutions. • These solutions provides two types of impuritydistribution namely constant source distribution namely constant source distribution following complimentary error function(erfc). • Constant sorce(erfc)distribution: • In this impurity distribution ,the impurity concentration at the semiconductor surface is maintained at a constant level throughout the diffusion cycle. • N(o,t)=Ns=constant • The soln to the diffusion equation which is applicable in this situation is most easily obtained by first considering diffusion inside a material in which the initial concentration changes in same plane as x=0,from Ns to 0.the eqn can be written as • N(o,t)Ns=constant and N(x,t)=0 • Shown below is a graph of the complementary error function for a range of values of its argument.