Lecture 1
Lecture 1
2.168
5.66
1.344
1.424 5.87
5.65
0.354
6.06
(a) A planar bonding diagram for a GaAs lattice, each bond consists of two valence electrons shared by a gallium and
an arsenic atom.
(b)The energy-band diagram in real space shows the valence-band edge E v below which all states are occupied, and
the conduction band edge Ec above which all states are empty. The separation Ec-Ev is the band gap Eg.
(c) A bonding diagram showing a broken bond due to the absorption of a photon with an energy above the band gap.
A free electron-hole pair is created. Note that the photogenerated electron is free to move around and the hole is
also free to hop around at different bonds between the Ga and As atoms.
(d)The energy-band diagram showing the energy levels of the electron and the hole.
Absorption and Emission
• Absorption of a photon-creation of an electron-
hole pair
hc 1.24
h ( eV ) E g =872 nm
• Spontaneous emission: an electron in the
conduction band recombines with a hole in the
valence band and excess energy emerges as a
photon
• Stimulated emission, in the presence of a photon
propagating in the semiconductor with electrons
in the conduction band and holes in the valence
band, the photon may stimulate the downward
transition of the electron from the conduction
band to the valence band and emit another
photon
Growth Techniques
• Molecular Beam Epitaxy (MBE)
• MOCVD (Metal-organic chemical vapor deposition)
• Lattice match
• Monolayer precision
• Heterojunction (GaAs/AlxGa1-xAs)
Ec
Ec
1.424eV Eg(x)
Ev
Ev
GaAs AlxGa1-xAs
Heterostructures
• Carrier and photon confinement
Energy
(eV)
Photon
Optical density
refractive
index
Growth direction
electrons holes
Band-gap engineering
• Fiber-optical communication: 1.33 m, 1.55 m
• Band-gap engineering, tune band gap of material to that
wavelengths
• InAs, Eg=0.354 eV, GaAs, Eg=1.424 eV
• In0.53Ga0.47As, Eg=0.8 eV, =1.55m, lattice matched to InP
• AlxGa1-xAs/GaAs material system
• a(AlxGa1-xAs)=xa(AlAs)+(1-x)a(GaAs)
• Eg(AlxGa1-xAs)= 1.424+1.247x (eV) for 0<x<0.4
Separate-confinement
heterostructure (SCH) quantum well
structure
Energy (eV)
• An actual energy band
diagram of GaAs/AlGaAS laser.
• 100 Å GaAs: active layer
• AlGaAs: cladding layer
(submicron in thickness)
• Improve device performance,
• lower threshold current,
• higher temperature stability,
• improved linewidth
enhancement factor,
Epitaxial layer growth direction • wavelength tunability, etc.
The tentative outline of the
lectures
Chapter 1: Wave nature of light (~2 weeks)