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Ethers
Characteristics and Function
Nice Joy L. Galero BSEd – Science 2A Ether
Any of a class of organic compounds
characterized by an oxygen atom bonded to two alkyl or aryl groups. Ethers are similar in structure to alcohols, and both ethers and alcohols are similar in structure to water. In an alcohol one hydrogen atom of a water molecule is replaced by an alkyl group, whereas in an ether both hydrogen atoms are replaced by alkyl or aryl groups. At room temperature, ethers are pleasant- smelling colourless liquids. Relative to alcohols, ethers are generally less dense, are less soluble in water, and have lower boiling points. They are relatively unreactive, and as a result they are useful as solvents for fats, oils, waxes, perfumes, resins, dyes, gums, and hydrocarbons. Vapours of certain ethers are used as insecticides, miticides, and fumigants for Ether Ethers are also important in medicine and pharmacology, especially for use as anesthetics. For example, ethyl ether (CH3CH2―O―CH2CH3), simply known as ether, was first used as a surgical anesthetic in 1842. Codeine, a potent pain-relieving drug, is the methyl ether of morphine. Because ether is highly flammable, it has largely been replaced by less-flammable anesthetics, including nitrous oxide (N2O) and halothane (CF3―CHClBr). Ethyl ether is an excellent solvent for extractions and for a wide variety of chemical reactions. It is also used as a volatile starting fluid for diesel engines and gasoline engines in cold weather. Dimethyl ether is used as a spray propellant and refrigerant. Methyl t-butyl ether (MTBE) is a gasoline additive that boosts the octane number and reduces the amount of nitrogen-oxide pollutants in the exhaust. The ethers of ethylene glycol are used as Check for Understanding Function of Ether Solvent: It’s a popular solvent for a wide variety of organic compounds, including fats, oils, and resins. Its low polarity makes it suitable for dissolving non-polar substances.
Reaction Medium: It’s used as a reaction
medium for various organic reactions, such as Grignard reactions and Williamson ether synthesis. Extraction: It’s used in liquid-liquid extraction to separate compounds based on their solubility.
Anesthesia: Historically, diethyl ether was
used as a general anesthetic, but its flammability and potential for side effects led to its replacement by safer alternatives . Fragrances and Perfumes:
Volatility: Ethers are often volatile,
meaning they evaporate easily. This makes them ideal for adding pleasant scents to products like perfumes, cosmetics, and soaps.
- Examples: Some ethers, like ethyl
acetate, are used as fragrance components. Medical Applications:
- Antiseptics: Some ethers have antiseptic
properties and are used in medical disinfectants.
- Medications: Ethers are sometimes
incorporated into the structures of drugs, influencing their properties. Industrial Applications:
Fuel Additives: Ethers like methyl tert-
butyl ether (MTBE) have been used as gasoline additives to increase octane rating.
Polymers: Ethers can be used to make
polymers, which are long chains of molecules. Thank You! Any Questions? Now let’s proceed to the Uses and Derivatives of Ethers!