4.1 Mod 4 - 1
4.1 Mod 4 - 1
Biomass energy
1. Concentrated wastes :
(i) Municipal solid (ii) Sewage wood products
(iii) Industrial waste (iv) Manure at large lots.
2. Dispersed waste residue :
(i) Crop residue (ii) Logging residue
(iii) Disposed manure.
3. Harvested biomass :
(i) Standing biomass (ii) Biomass energy plantations
PHOTOSYNTHESIS
• CO2 from the atmosphere combines with water and light energy to produce
carbohydrates (i.e., sugars, starches etc.) and oxygen.
(ii) CO2 concentration : CO2 is the primary raw material for photosynthesis.
The main sources of CO2 are :
— Animal respiration;
— Combustion of fuel;
— Ocean (respiration of marine plants and animal releases CO2 into the water).
(iii) Temperature : The process of photosynthesis is restricted to temperature
range of 0°C to 60°C which can by tolerated by proteins.
BIOMASS FUELS
• Often it is transformed into modern energy forms such as liquid and gaseous
fuels, electricity, and process heat to provide energy services needed by rural
and urban populations and also by industry.
• This was the main source of energy used by mankind for centuries.
• Direct combustion is the simplest way to obtain heat energy. Its energy density is 16–
20 MJ/kg.
• It can also be converted to more useful forms such as charcoal or producer gas.
2.Charcoal
• It has 75–80 per cent carbon content and has energy density of about 30 MJ/kg.
• Chemical grade charcoal has many uses in laboratory and industrial chemical
processes.
• Crop residues such as straw, rice husk etc. and waste wood are pressed to form
lumps, known as fuel pellets or briquettes and used as solid fuel.
• The purpose is to reduce moisture content and increase the energy density
of biomass making it more feasible for long distance transportation.
4. Bio-diesel
• Some vegetable oils, edible as well as non-edible can be used in pure form or
its blend with petroleum diesel as fuel in a compression–ignition (diesel)
engine.
• It can be derived from wet biomass containing sugars (e.g. sugarcane, sugarbeet,
sweet sorghum, etc.), starches (grains, tubers such as potato, cassava, etc.) or
cellulose (woody matter).
• Main constituents of woody matter are: lignin (fibrous part) and cellulose (juicy
part).
7. Producer Gas
• Woody matter such as crop residue, wood chips, bagasse (fibrous residue of
sugar cane after juice extraction), rice husk, coconut shell, etc., can be
transformed to producer gas (also known as synthesis gas, syn gas, wood gas,
and water gas or bluegas) by a method known as thermal gasification of solid
fuel.
BIOMASS CONVERSION TECHNOLOGIES
• There are many different ways of extracting energy from biomass. These energy
conversion technologies may be grouped into four basic types:
• Its density is increased by reducing the volume using compression through the
processes called ‘briquetting’ and ‘pelletization’.
• The heat produced are either used to generate electricity or provide the heat for
industrial process, space heating, cooking or district heating.
• Furnaces and boilers have been developed for large scale burning of various
types of biomass such as wood, waste wood, black liquid from pulp industry,
food industry waste .
• The moisture content in the biomass and wide range of
composition tends to decrease the efficiency of conversion.
(iii) Thermo-Chemical
• Biomass is heated either in absence of oxygen or by partial combustion of some of the biomass
in restricted air or oxygen supply.
1. PYROLYSIS
• Pyrolysis can process all forms of organic materials including rubber and plastics, which
cannot be handled by other methods.
• The products are three types of fuels, usually: a gas mixture (H2, CO, CO2, CH4 and N2), oil like
liquid (water soluble phase including acetic acid, acetone, methanol and non-aqueous phase
including oil and tar) and a nearly pure carbon char.
• The distribution of these products depends upon the type of feedstock, the temperature and
pressure during the process and its duration and the heating rate.
2. GASIFICATION
• High temperature pyrolysis (~1000 °C) maximizes the gaseous product. The process is known as
gasification.
3. CARBONIZATION
• Low temperature pyrolysis (up to 600 °C) maximizes the solid output. The process has been used
4. LIQUEFICATION
• Liquid product is obtained through catalytic liquefaction process. Liquefaction is a relatively low
temperature (250–450 °C), high pressure (270 atm) thermo-chemical conversion of wet biomass,
usually with high hydrogen partial pressure and also a catalyst to enhance the rate of reaction
of air of simple hexose sugars (sugars containing six carbon atoms per molecule,
• This process converts decaying wet biomass and animal wastes into biogas
through decomposition process by the action of anaerobic bacteria (bacteria
that live and grow in absence of oxygen).
• Carbon present in biomass may be ultimately divided between fully oxidized CO2
and fully reduced CH4. Thus:
• The biomass material in the form of water slurry is digested by the bacteria
anaerobically for several days in an airtight container.
• The reactions are slightly exothermic and small amount of heat
(equivalent to 1.5 MJ per kg dry digestible material) is also generated that
helps in maintaining favorable temperature.
• Disposal of MSW is a major problem in big cities where large quantities of waste is to be disposed
of, far away from the city centers.
• The emerging solution is to use this waste biomass as an energy resource in a waste-to-energy
conversion plant near city center.
• The energy thus generated is used within city itself and only a relatively small residue of used
biomass (ash etc.) is disposed away in landfills.
• Through incineration or gasification, electrical energy may be generated along with thermal energy
for process heat.
• The composition of urban waste depends on the style and standard of living
of the people.
• The energy content of domestic refuse differs significantly from area to area.
Generally it lies in range 4.2 to 14 MJ/kg.
• The dry biomass is shredded to pieces
of about 2.5 cm diameter.
• An air stream segregates refuse derived
fuel (RDF), which is lighter from heavier metal
and glass pieces.
• The heavier part is reclaimed and recycled.
• The RDF thus obtained is burnt in the furnace
at about 1000 °C to produce steam in the boiler.
• Combustion process may be assisted by required
amount of auxiliary fuel when RDF does not burn
properly by itself.
• The superheated steam obtained from boiler is
used in a steam turbine coupled with an
alternator to produce electrical output in the
same way as in a conventional thermal plant.
• The flue gases are discharged to atmosphere
through stack after removal of pollutants such
as particulate matter, SOx and NOx, etc.
• Heat recovery steam generator extracts maximum
MSW to energy incineration plant possible heat from flue gases to form thermal output.
The ash is removed and disposed of to landfills.
Problems associated with incineration plants
• Because of various materials contained in the waste stream, pollutants in the flue
gases include derivatives of sulphur, chlorine, fluorine, nitrogen, chlorinated
hydrocarbons and heavy metals.
• It has been proven to cause cancer in animals and is linked with a variety of
other health problems, including genetic defects.
• PCDD/PCDF are formed either in the combustion chamber or after combustion
when the gases cool in the exhaust stack.
• Disagreement continues over establishing safe levels of dioxins emission from any
incinerator.
2. The residual ash, which has high metal concentration, is also of concern.
• The ash is usually disposed of in landfills; the leachate (garbage juice; liquid that
results when water percolates through the landfill) must be well contained to prevent
groundwater contamination
Typical metal concentrations in fly ash and bottom ash of an incinerator
BIOMASS GASIFICATION
• The word gasification (or thermal gasification) implies converting solid fuel into a
gaseous fuel by thermo-chemical method without leaving any solid carbonaceous
residue.
• Most common raw materials are: wood chips and other wastes from wood industry,
coconut shells, straw etc.
• Gasification involves partial combustion (oxidation in restricted quantity of
air/oxidant) and reduction operations of biomass.
• The combustion products, mainly carbon dioxide, water vapour, nitrogen, carbon
monoxide and hydrogen pass through the glowing layer of charcoal for the reduction
process to occur.
• During this stage both carbon dioxide and water vapour, oxidize the char to form CO,
H2 and CH4.
• Thus the product of combustion of pyrolysis gases results in CO2 and H2O (steam),
which further react with char:
• The composition of the gas produced depends on the degree of equilibrium attained
among various reactions.
• Gasifiers are broadly classified into:
• The fixed bed gasifiers are further classified depending upon the direction of airflow as:
(a) downdraft
(b) updraft
• Oxidation zone is below the pyrolysis zone, and reduction zone is below the
oxidation zone.
• Its main advantage is that the producer gas is produced with low tar content,
which will be suitable for gas engines.
• The position of the oxidation zone is thus a critical parameter in the design of
downdraft gasifier.
b. Updraft Type
• Updraft type gasifier (also called counter flow gasifier) is the
simplest as well as first type of gasifier developed.
• This type of gasifier is easy to build and operate.
• The air enters below the combustion zone and the gas is
drawn off at the top.
• The updraft gasifier achieves highest efficiency as the hot gas
passes through the fuel bed and then leaves the gasifier at
low temperature.
• The gas produced has practically no ash but contains tar
and water vapor because of passing of gas through unburnt
fuel.
• Hence updraft gasifier is suitable for tar free feedstock (fuels
like charcoal, etc.).
• It is most unsuitable for high volatile fuels. The zones of
various reactions are shown in Fig.
c. Crossdraft Type
• Because of short path length for gasification reactions, this type of gas
producer responds most rapidly for change in gas production.
• The high exit temperature of the gas and low CO2 reduction results in
poor quality of gas and low efficiency.
• Carbohydrates (also known as saccharides) can be divided into three major classes
in order of increasing complexity.
(a) Monosaccharides
• More precisely glucose and fructose can be represented by formulae HCO – (HCOH)
4 – CH2OH and CH2OH – CO – (HCOH) 3 – CH2OH respectively.
• Glucose occurs naturally in sweet fruits (e.g. ripe grapes), honey, etc.
(b) Oligosaccharides
• For example, disaccharide (such as sucrose, maltose, etc., both having formula
C12H22O11) produces two monosaccharide molecules on hydrolysis.
• These are high molecular mass carbohydrates, which yield large number of
monosaccharides molecules on hydrolysis.
• Examples are starch and cellulose, both having general formula (C6H10O5)n. Large
numbers (few hundreds to few thousands) of glucose units are joined together in a
complex chain.
• Starch occurs naturally in all plants, particularly in seeds. The main sources are
maize, barley, rice, wheat, potato, cassava and sorghum, etc.
• Cellulose is main constituent of cell walls of the plants. Wood contains 45–50 per cent
while cotton contains 90–95 per cent cellulose.
• In general monosaccharides and oligosaccharides are crystalline solids,
soluble in water and sweet in taste. These are collectively known as sugars.
• The hexose (glucose and/or fructose) required for ethanol fermentation is derived
from: (a) sucrose (b) starch or (c) cellulose.
PREPARATION OF ETHANOL
(a) From Sucrose
• Usually commercial sucrose is removed from the cane juice, and the remaining molasses,
which has low commercial value, is used for ethanol production.
• The molasses itself has about 55 per cent sugar content and serves as very good raw
material for ethanol production.
• On hydrolysis with dilute acids or enzyme it gives equal amounts of glucose and fructose.
(b) From Starch
• On hydrolysis with dilute H2SO4 or enzyme, starch breaks down to maltose and
finally to glucose.
• This second distillation process is energy intensive process and accounts for about 40–60
per cent of the total plant energy requirements.
• Various steps involved in production of ethanol from the three types of biomass
resources are shown in Fig.
Ethanol production from various types of biomass
BIOGAS PRODUCTION FROM WASTE BIOMASS
• Biogas is produced from wet biomass with about 90–95 per cent water content by the
action of anaerobic bacteria (bacteria that live and grow in absence of oxygen).
• Part of carbon is oxidized and another part reduced to produce CO2 and CH4.
• These bacteria live and grow without oxygen. They derive the needed oxygen by
decomposing the biomass.
• The airtight equipment used for conversion is known as biogas plant or digester,
which is constructed and controlled to favor methane production
• Nutrients such as soluble nitrogen compounds remain available in solution and
, provide excellent fertilizer and humus.
• The energy available from the combustion of biogas is 60–90 per cent of the
input dry matter heat of combustion.
• Thus the energy conversion efficiency of the process is 60–90 per cent.
5. Modified fixed dome type biogas plant – This type of plant has an additional
displacement tank and water seal gas tank.
1. Continuous Type Biogas Plant
• In this type of plant the biomass is fed regularly to the digester and it supplies the gas
continuously.
These are two types of continuous biogas plant :
1. Single stage type 2. Two stage type
1. Single stage continuous biogas plant. Entire process of conversion of biomass into biogas are
carried in a single digester. This chamber is regularly fed with the raw materials while the spent
residue keeps moving out.
Advantages :
• Simple in construction.
• It does not need skilled labour.
• It is easy to operate and control.
• These are preferred for small and medium sized biogas plants.
• Serious problems are encountered with agricultural residues when fermented in a single stage
continuous process.
2. Two stage continuous type biogas plant.
These plants have two digesters for digestion of biomass. In the ‘first digester’ the biomass is
fed in which the acid production is carried out and then only dilute acids are fed into the
‘second digester‘ where bio-methanation takes place and biogas can be collected from the
second digester/chamber.
Advantages :
• It produces more gas than the single stage plants.
• It requires lesser period of digestion as compared to single stage plants.
• These plants are preferred for large size biogas plants.
Advantages of continuous type biogas plants :
Following are the advantages of continuous type biogas plants :
1. Continuous gas production.
2. Less retention period.
3. Small digestion chambers required.
4. Less problems as compared to batch type plants.
2.Batch Type Biogas Plant
• In a batch type plant, the biomass feeding is done in batches with large time
interval between two consecutive batches.
• A batch loaded digester is filled to its capacity and given sufficient retention
time (35 to 45 days) for digestion of biomass.
• After the completion of digestion, the residue is emptied and filled again.
• Gas production is ‘uneven’ due to slow start of bacterial digestion and to
overcome this difficulty, several digesters are used which are fed and emptied
insequential manner. Thus, the regular supply of gas is maintained.
“Salient features” of batch type plant are :
1. Gas production uneven/intermittent, depending upon the cleaning of the digester.
2. Several digesters required, to get continuous supply of gas.
3. High space requirements, due to several digesters.
4. High initial cost, due to large volume of digester.
3.Floating Drum Type Biogas Plant
• It moves up and down depending upon accumulation and discharge of gas guided by
the domeguide itself.
• Digester. It is underground cylindrical wall portion made of bricks, sand and cement. It is this
place where fermentation of dung takes place. It is also sometimes called ‘fermentation tank’.
Two rectangular openings facing each other are provided for inflow and outflow at almost
middle of its height.
• Dome. It is a hemispherical roof of the digester; has a fixed height and forms the critical part
in the construction of Janata gobar gas plant. The gas gets collected in the space of the dome
and exerts pressure on the slurry in the digester.
• Inlet chamber.An inlet chamber has a bell mouth shape and is made of bricks,
cement and sand. It has its top opening at the ground level. Its outlet wall is made
inclined/slopy to enable the daily cattle dung feed to move easily into the digester.
• Outlet chamber. It is that part of the plant through which digested slurry moves
out of the digester at a predetermined height. It has a small rectangular cross-
section and above this it becomes larger to a defined height.
For easy cleaning of the digester two steps are provided in it which enable a man
to climb down. Its top opening is also at the ground level. Just near the top
opening is provided a small outlet through which the digested/spent slurry flows
to a compost pit.
• Mixing tank. It is this tank where dung and water are mixed properly in the ratio
of 1 : 1 to make slurry which is then poured into the inlet chamber.
• Gas outlet pipe. It is a small piece of G.I. Pipe which is fitted at the top of the
dome for conveying the gas to the points of use. A valve is fitted at its end to
regulate the flow of gas to the gas connections.
Advantages and disadvantages of “Fixed dome type plants”
Advantages :
• No maintenance problems due to absence of moving parts.
• Low cost.
• Low operating cost.
• Longer working life.
• Due to underground construction, heat insulation is better and therefore, rate of
gas production is uniform during night and day.
• Quantity of gas producd is higher than movable drum type plants.
• No corrosion problem.
• Space above the plant can be used for other purposes.
Disadvantages :
• Variable gas pressure.
• Gas production per cm3 of the digester volume is less.
• Problem of scum formation.
• For construction work skilled masons are required.
5.Modified Fixed Dome type
(Deenbandhu Biogas Plant (DBP))
• This is fixed dome plant developed by Action for Food Production (AFPRO) in
1984.
• It is appropriate for all types of wastes and minimizes biogas losses from inlet
chamber.
Construction. It has ‘curved bottom’
and ‘hemispherical top’ which are joined
at their bases with no cylindrical portion
in between. An ‘inlet pipe’ connects
‘mixing tank’ with the‘digester’.
• Working. Cattle dung slurry prepared in 1 : 1 ratio with water is fed upto the level
of second step in the outlet tank.
• As the gas generates and accumulates in the empty portion of the plant, it presses
the slurry of the digester and displaces it into the outlet ‘displacement chamber’.
• The slurry level in the digester falls whereas in the outlet chamber it starts rising.
• This fall and rise continues till the level in the digester reaches the upper end of
the outlet opening and at this stage the slurry level in the outer tank reaches the
height of discharge opening.
Advantages :
• This plant required less space being mainly underground.
• Its cost is reduced as the surface area is minimised by joining segments of two
different diameter spheres at their bases.
• It is 30 percent economical as compared to Janata biogas plant.
Comparison Between Fixed Dome Type and Movable
Drum Type Biogas Plants