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Presented by Atif mumraiz
Roll no 211327 Subject chemistry Govt Post Graduate Colloge Haripur Chemistry of hydrocarbons 4 major portions • Alkanes. • Alkenes. • Alkynes. • Benzene. Hydrocarbon
Those compound which consist of C and H are called
hydrocarbons. Alkynes They are unsaturated hydrocarbons which contain carbon carbon triple bond. And no 2 things the simplest alkynes is ethyne ( Acetylene). Formula Why alkene alkyne and benzene are nucleophile. Alkene alkyne and benzene are nucleophile bcz they contain Pi electron system so the electrophile attack on these nucleophile. Which of following nucleophile has more attack of electrophile • Alkene. • Alkyne. • Benzene. • Alkane. Another factor for reactivity • bond energy bond energy is directly related to stability and inversely related to reactivity. Bond energy of alkyne is 839kj per mole while bond energy of alkenes is 616kjper mole . • It is possible alkyne is more reactive then alkene. • There are two major cases in which alkyne is more reactive then alkene. • catalytic hydrogenation. • Nucleophilic addition. Preparation of alkynes Dehydrohalogenation of dihalides De ( remove) Hydro (hydrogen) Halogenation halogen. Reagent • 2 reagent • Alcoholic Koh • Sodium amide Types of dihalide • 2 types • vicinal dihalide • germinal dihalide Vicinal dihalide dihalide having two halogen atom on adjacent position called vicinal dihalide. Geminal dihalides dihalide having two halogen atom on the same carbon is called geminal dihalides General reaction of dihalides Question • what is terminal alkyne. • Alkyne have 4pi electron but why it is less reactive as compare to alkene which has 2 pi electron. • Why don not every electrophile attack on benzene. • Which factor is which alkyne are more reactive then alkene. • Why dehydrohalogenation is called double dehydrohalogenation • Why it is difficult to remove 2nd HX from dihalide. THANK YOU