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Hydro Corb On

It clearly explain what is hydrocarbon and general introduction of alkyne with its reactivity clearly with examples and it's preparation

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0% found this document useful (0 votes)
9 views23 pages

Hydro Corb On

It clearly explain what is hydrocarbon and general introduction of alkyne with its reactivity clearly with examples and it's preparation

Uploaded by

atifmumraiz178
Copyright
© © All Rights Reserved
We take content rights seriously. If you suspect this is your content, claim it here.
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Presented by Atif mumraiz

Roll no 211327
Subject chemistry
Govt Post Graduate Colloge Haripur
Chemistry of hydrocarbons
4 major portions
• Alkanes.
• Alkenes.
• Alkynes.
• Benzene.
Hydrocarbon

Those compound which consist of C and H are called


hydrocarbons.
Alkynes
They are unsaturated hydrocarbons which contain carbon
carbon triple bond.
And no 2 things the simplest alkynes is ethyne ( Acetylene).
Formula
Why alkene alkyne and benzene are
nucleophile.
Alkene alkyne and benzene are nucleophile bcz they contain Pi
electron system so the electrophile attack on these
nucleophile.
Which of following nucleophile has more
attack of electrophile
• Alkene.
• Alkyne.
• Benzene.
• Alkane.
Another factor for reactivity
• bond energy
bond energy is directly related to stability and inversely
related to reactivity.
Bond energy of alkyne is 839kj per mole while bond energy of
alkenes is 616kjper mole .
• It is possible alkyne is more reactive then alkene.
• There are two major cases in which alkyne is more reactive
then alkene.
• catalytic hydrogenation.
• Nucleophilic addition.
Preparation of alkynes
Dehydrohalogenation of dihalides
De ( remove)
Hydro (hydrogen)
Halogenation halogen.
Reagent
• 2 reagent
• Alcoholic Koh
• Sodium amide
Types of dihalide
• 2 types
• vicinal dihalide
• germinal dihalide
Vicinal dihalide
dihalide having two halogen atom on adjacent position called
vicinal dihalide.
Geminal dihalides
dihalide having two halogen atom on the same carbon is
called geminal dihalides
General reaction of dihalides
Question
• what is terminal alkyne.
• Alkyne have 4pi electron but why it is less reactive as
compare to alkene which has 2 pi electron.
• Why don not every electrophile attack on benzene.
• Which factor is which alkyne are more reactive then alkene.
• Why dehydrohalogenation is called double
dehydrohalogenation
• Why it is difficult to remove 2nd HX from dihalide.
THANK YOU

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