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FIRST_REVIEW_BATCH_MP_ppt

The document outlines a project focused on the preparation and characterization of core-shell nanoparticles, specifically zinc oxide (ZnO) embedded in silicon dioxide (SiO2), to enhance their catalytic activity through photo-sonocatalytic processes. It identifies challenges related to the stability and efficiency of ZnO nanoparticles and proposes methodologies for synthesis, characterization, and testing of their catalytic performance. The project includes a literature review and discusses existing and proposed methodologies for synthesizing these nanoparticles.

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Naveen
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6 views

FIRST_REVIEW_BATCH_MP_ppt

The document outlines a project focused on the preparation and characterization of core-shell nanoparticles, specifically zinc oxide (ZnO) embedded in silicon dioxide (SiO2), to enhance their catalytic activity through photo-sonocatalytic processes. It identifies challenges related to the stability and efficiency of ZnO nanoparticles and proposes methodologies for synthesis, characterization, and testing of their catalytic performance. The project includes a literature review and discusses existing and proposed methodologies for synthesizing these nanoparticles.

Uploaded by

Naveen
Copyright
© © All Rights Reserved
Available Formats
Download as PPTX, PDF, TXT or read online on Scribd
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ERODE SENGUNTHAR ENGINEERING COLLEGE

(An Autonomous Institution)


Approved by AICTE, New Delhi, Permanently Affiliated to Anna University- Chennai,
Accredited by National Board of Accreditation (NBA), New Delhi &
National Assessment and Accreditation Council (NAAC), Bangalore with ‘A’ Grade
PERUNDURAI -638 057, TAMILNADU, INDIA.

PREPARATION AND CHARACTERIZATIONS OF CORE SHELL


NANOPARTICLE AND ENHANCING THE CATALYTIC ACTIVITY BY PHOTO-
SONOCATALYTIC PROCESSES

Presented by Guided by
ARTHISH K Mrs. AATRAL G V
MUTHU ASSISTANT PROFESSOR
KRISHNAN S DEPARTMENT OF CHEMICAL ENGINEERING
NANDISWARAN P ERODE SENGUNTHAR ENGINEERING COLLEGE
PRAKATH SENA M
TABLE OF CONTENT

S.NO CONTENT
1 INTRODUCTION
2 IDENTIFICATION OF PROBLEM
3 LITERATURE REVIEW
4 BASE PAPER
5 EXISTING METHODOLOGY
6 PROPOSED METHODOLOGY
INTRODUCTION
Core-shell nanoparticles are a class of nanoparticles that consist of a core material
surrounded by a shell material.
The core and shell materials can be made of different materials, such as metals,
semiconductors, or polymers.
The unique properties of core-shell nanoparticles arise from the combination of the core
and shell materials, which can exhibit synergistic effects.
Zinc oxide (ZnO) nanoparticles have been extensively explored for their catalytic,
optical, and electrical properties. However, their bare surfaces often suffer from
aggregation, photodegradation, and reduced catalytic activity. To address these
limitations, embedding ZnO nanoparticles within a silica (SiO2) shell has emerged as a
promising strategy. The SiO2 shell not only stabilizes the ZnO core but also enhances its
catalytic activity and durability.
IDENTIFICATION OF PROBLEM

The problem focuses on enhancing the catalytic activity of core-shell nanoparticles,


specifically zinc oxide (ZnO) embedded in silicon dioxide (SiO2). The challenge lies in
improving the efficiency and stability of these nanoparticles for various catalytic
applications, such as environmental pollution control and energy conversion. ZnO, while an
effective catalyst, often suffers from limitations such as poor stability, low catalytic activity
under standard conditions, and the tendency for surface deactivation. The incorporation of
photo-sonocatalytic processes (using light and ultrasound together) is proposed to enhance
the catalytic performance and increase efficiency.
LITERATURE REVIEW
Azmina, M. S., et al. "Enhanced photocatalytic activity of ZnO nanoparticles grown on
porous silica microparticles." Applied Nanoscience 7 (2017): 885-892.
Yin Jiang,et al,(2009) the ZnO nanoparticles by a simple hydrothermal method and
fabricated the ZnO/SiO2 core/shell nanostructures through a sol–gel chemistry process
successfully.
Imam Sahroni,et al,(2021)the synthesis of ZnO/SiO2 nanocomposites using bamboo leaf
ash (BLA) and tested their photocatalytic activity for rhodamine B decolorization have been
conducted.
Jing Zhai,et al,(2010) ZnO nanoparticles were prepared by a simple chemical synthesis
route. Subsequently, SiO2 layers weresuccessfully coated onto the surface of ZnO
nanoparticles to modify the photocatalytic activity in acidic or alkaline solutions.
Harish, S., et al. "Synthesis of ZnO/SrO nanocomposites for enhanced photocatalytic
activity under visible light irradiation." Applied surface science 418 (2017): 147-155.
d’Água, Raquel Borda, et al. "Efficient coverage of ZnO nanoparticles on cotton
fibres for antibacterial finishing using a rapid and low cost in situ synthesis." New
Journal of Chemistry 42.2 (2018): 1052-1060.
Barani, Hossein. "Preparation of antibacterial coating based on in situ synthesis of
ZnO/SiO2 hybrid nanocomposite on cotton fabric." Applied Surface Science 320
(2014): 429-434.
Ba-Abbad, Muneer M., et al. "Synthesis and characterization of Sm 3+-doped
ZnO nanoparticles via a sol–gel method and their photocatalytic application."
Journal of Sol-Gel Science and Technology 85 (2018): 178-190.
Mohamed, Amina L., et al. "Laminating of chemically modified silan based
nanosols for advanced functionalization of cotton textiles." International Journal
of Biological Macromolecules 95 (2017): 429-437.
BASE PAPER

A base paper for this project could be one that covers the synthesis and
applications of ZnO/SiO2 core-shell nanoparticles, the sol-gel process for
nanoparticle synthesis, and the use of photo-sonocatalysis in catalysis
El-Naggar, Mehrez E., et al. "Surface modification of SiO2 coated ZnO
nanoparticles for multifunctional cotton fabrics." Journal of colloid and interface
science 498 (2017): 413-422.
Zhai, Jing, et al. "Core/shell structured ZnO/SiO2 nanoparticles: preparation,
characterization and photocatalytic property." Applied Surface Science 257.2
(2010): 393-397.
EXISTING METHODOLOGY

 Chemical Methods
1. Sol-Gel Method: Involves hydrolysis and condensation of metal alkoxides to
form a metal oxide shell around a core material.
2. Hydrothermal Method: Involves reaction of metal salts in a high-temperature
aqueous solution to form a metal oxide shell around a core material.
3. Microemulsion Method: Involves using microemulsions to synthesize core-shell
nanoparticles.
4. Polyol Method: Involves using polyols as reducing agents to synthesize metal
nanoparticles.
Physical Methods
1. Layer-by-Layer Assembly: Involves sequential deposition of layers of different
materials to form a core-shell structure.
2. Sputtering: Involves bombarding a target material with high-energy ions to
deposit a thin film on a substrate.
3. Electroplating: Involves depositing a thin film of a material on a conductive
substrate using an electric current.
Biological Methods
1. Biosynthesis: Involves using microorganisms or plants to synthesize
nanoparticles.
2. Bio-inspired Synthesis: Involves using biomolecules as templates or reducing
agents to synthesize nanoparticles.
PROPOSED METHODOLOGY

1. SYNTHESIS OF ZNO/SIO2 CORE-SHELL NANOPARTICLES


 Preparation of zno nanoparticles, zno nanoparticles are synthesized using the sol-
gel method by dissolving zinc acetate in ethanol and adding a suitable stabilizing
agent. The solution undergoes hydrolysis, followed by heat treatment to form zno.
 Coating with sio2 shell, the zno nanoparticles are coated with sio2 by adding
tetraethyl orthosilicate (teos) to the sol-gel mixture and adjusting the ph to promote
hydrolysis and condensation. The core-shell structure is formed by calcining the
particles at a suitable temperature.
2. CHARACTERIZATION OF CORE-SHELL NANOPARTICLES
 Structural characterization, XRD, SEM, and TEM are used to analyze the size,
morphology, and structural integrity of the zno/sio2 nanoparticles.
 Optical and surface properties, uv-vis spectroscopy and ftir are used to evaluate
the optical properties and surface characteristics of the particles.
3. CATALYTIC TESTING
 Photo-sonocatalytic activity, the catalytic activity of the zno/sio2 nanoparticles
will be tested in the degradation of organic pollutants (e.G., Dyes) under UV light
and ultrasonic irradiation. The performance will be evaluated by monitoring the
degradation rate over time using spectrophotometric analysis.
 Synergistic effect of photo-sonocatalysis, experiments will compare the catalytic
efficiency of zno/sio2 nanoparticles under uv light, ultrasonic waves, and
combined photo-sonocatalysis to determine the best method for enhancing
catalytic activity.
THANK
YOU

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