The document provides an overview of mixtures, classifying them as homogeneous or heterogeneous, with examples for each category. It also explains solutions, their components (solute and solvent), and various concentration measures such as percent by mass, mole fraction, molarity, molality, percent by volume, and parts per million (PPM), along with sample problems for calculation. Additionally, it discusses the heat of solution and factors influencing dissolution processes.
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The document provides an overview of mixtures, classifying them as homogeneous or heterogeneous, with examples for each category. It also explains solutions, their components (solute and solvent), and various concentration measures such as percent by mass, mole fraction, molarity, molality, percent by volume, and parts per million (PPM), along with sample problems for calculation. Additionally, it discusses the heat of solution and factors influencing dissolution processes.
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Solutions
Activity: (10-15 minutes)
Classify each mixture as HETEROGENEOUS or HOMOGENEOUS and write a brief explanation of why they made their choice for each. HOMOGENEOUS HETEROGENEOUS MIXTURE MIXTURE Answer key •Saltwater - Homogeneous •Granite - Heterogeneous •Salad - Heterogeneous •Tea - Homogeneous •Air - Homogeneous •Chocolate chip cookie •Concrete - Heterogeneous dough - Heterogeneous •Oil and vinegar dressing - •Wood - Heterogeneous Heterogeneous •Soft drink - Homogeneous •Blood - Heterogeneous •Air freshener spray - •Milk - Homogeneous Homogeneous •Sand and water - •Pizza - Heterogeneous Heterogeneous Mixtures • made up of two or more components. • can either be homogeneous or heterogeneous. HOMOGENEOUS HETEROGENEOUS MIXTURE MIXTURE • only one phase is visible • having components with different sizes and shapes and contains two or more visible phases Solutions • are homogeneous mixtures, which are composed of a solute and a solvent. • Solute- the substance that is present in small amounts. • Solvent- the bulk or the medium in which the solute is dissolved or mixed, or dispersed. •Solutions that use water as solvent are considered aqueous solutions. Aqueous solutions can be classified as electrolytes or nonelectrolytes, depending on the presence of ions in the solution. Those that can conduct electricity re considered electrolytes. •Nonelectrolytes, on the other hand, are solutions that do not conduct electricity. Examples include aqueous solution of glucose or isopropyl alcohol. Heat of Solution (Hsoln) •accounts for the overall change in the energy associated the formation of solution. This is taken as the sum of the energy change derived from each stage. May either be a positive sign or a negative sign Generally, a more negative value of (Hsoln) or a favorable dissolution process, is influenced by the following: •Strong solvent-solute attractions •Weak solute-solute interaction •Weak solvent-solvent interactions Concentration of Solution Concentration of Solution •the amount of solute dissolved in a given quantity of solvent or solution. Percent by Mass (% by Mass) •The mass of the solute divided by the total mass of the solution, multiplied by 100. Sample Problem: •A solution contains 5 g of salt dissolved in 95 g of water. Calculate the percent by mass. Sample Problem: •If 20 g of sugar is dissolved in 180 g of water, what is the percent by mass of sugar? Mole Fraction (X) •The ratio of the number of moles of one component to the total number of moles of all components in the solution. Sample Problem: •Calculate the mole fraction of NaCl in a solution with 2 moles of NaCl and 8 moles of water. Sample Problem: •Determine the mole fraction of ethanol (C2H5OH) in a solution containing 3 moles of ethanol and 7 moles of water. Sample Problem: •a solution is made by dissolving 1.25 g Na2SO4 in 65 g water. calculate the mole fraction of the solute and the solvent Molarity (M) •The number of moles of solute per liter of solution. Sample Problem: •Find the molarity of a solution with 2 moles of solute in 4 liters of solution. Sample Problem: •A solution contains 0.5 moles of solute in 250 mL of solution. Calculate the molarity. Sample Problem: •A solution contains 78.2 g NaCl dissolved in sufficient water to give a total volume of 0.525 L. what is the molarity of the solution? Molality (m) •The number of moles of solute per kilogram of solvent. Sample Problem: •Calculate the molality of a solution with 3 moles of solute dissolved in 2 kg of solvent. Sample Problem: •If 0.1 moles of solute are dissolved in 500 g of solvent, find the molality. Sample Problem: •A solution contains 22.5 g of methanol (CH3OH) dissolved in sufficient water to give a total mass of 105.3 g. what is the molality of the aqueous methanol solution? Percent by Volume (% by Volume) •The volume of the solute divided by the total volume of the solution, multiplied by 100. Sample Problem: •A solution contains 30 mL of ethanol in 120 mL of solution. Calculate the percent by volume. Sample Problem: •If 50 mL of isopropanol is mixed with 200 mL of solution, what is the percent by volume? Parts Per Million (PPM) •The number of parts of solute per million parts of the solution. Sample Problem: •A solution contains 0.002 g of solute in 1 kg of solution. Calculate the PPM. Sample Problem: •If 5 mg of solute is dissolved in 2 liters of water (density = 1 g/mL), find the PPM. Sample Problem: •A water sample contains 0.008 g of lead (Pb) in 4.0 liters of water. Calculate the concentration of lead in PPM. ACTIVITY