instrumentation pseudofirst order reaction aza and thia variants of rearrangement there equilibrium process base catalysed reaction narrowing of airway shortness of breath cough difficulties in breathing pathophysiology leukotriene antagonist corticosteroids methyl xanthines inhalers sympathomimetics anticholinergics treatment algorithm mast cell stabilizers inflammation bronchioles pharmaceutical analysis uv-visible spectroscopy single beam spectrophotometer double beam spectrophotometer beer-lambert's law absorption spectroscopy spectroscopy pharmacy analytical technique qualitative analysis quantitative analysis light sources in uv spectroscopy monochromators detectors in uv spectroscopy 1 2- brook rearrangement 1 2-silyl migration silyl ether oxysilane generation of alpha-silyl alkoxide capillary electrophoresis mass spectrometry electrophoretic mobility interface capillary electroosmotic flow electric field silanol groups cathode anode zeta potential electrospray ionization sheath flow interface sheathless interface liquid juction interface continuous flow fast atom bombardment matrix assisted laser desorption ionization off-line coupling on-line coupling mass analyser inflammatory mediators ion exclusion ion exclusion partition chromatography chromatographic technique donnan exclusion chromatography donnan exclusion mechanism wheaton bauman stationary phase mobile phase resin phase occluded liquid phase separation of aliphatic carboxylic acids trapped liquid column cation exchange resin anion exchange resin exclusion or repulsion adsorption eluent delivery system
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