![SAFETY DATA SHEET
according to Regulation (EC) No. 1907/2006
Enviromite 480SC
Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011
SAP 6.0 2 / 15 SDS Number: 400000004589
Labelling (REGULATION (EC) No 1272/2008)
Labelling according to EC Directives ()
Hazard pictograms :
Irritant Dangerous
for the
environment
R-phrase(s) : R43 May cause sensitization by skin contact.
R51/53 Toxic to aquatic organisms, may cause
long-term adverse effects in the aquatic
environment.
S-phrase(s) : S24 Avoid contact with skin.
S37 Wear suitable gloves.
S57 Use appropriate container to avoid
environmental contamination.
S61 Avoid release to the environment. Refer to
special instructions/ Safety data sheets.
Hazardous components which must be listed on the label:
149877-41-8 Bifenazate
2.3 Other hazards
No information available.
3. Composition/information on ingredients
3.2 Mixtures
Chemical nature : Acaricide
Hazardous components
Chemical Name CAS-No.
EC-No.
Registration
number
Classification
(67/548/EEC)
Classification
(REGULATION
(EC) No
1272/2008)
Concentration
[%]
Bifenazate 149877-41-8
442-820-5
Xi-N; R43-R50/53 Skin Sens. 1; H317
STOT RE 2; H373
Aquatic Acute 1;
H400
43.46
propane-1,2-diol 57-55-6
200-338-0
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Enviromite 480 sc (english sds)
- 1. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 1 / 15 SDS Number: 400000004589 1. Identification of the substance/mixture and of the company/undertaking 1.1 Product identifier Trade name : Enviromite 480SC 1.2 Relevant identified uses of the substance or mixture and uses advised against Use of the Substance/Mixture : Plant protection agent, Acaricide 1.3 Details of the supplier of the safety data sheet Company: Chemtura Manufacturing UK Limited Tenax Road, Trafford Park Manchester United Kingdom M17 1WT Customer Service: +44 161 875 3800 Prepared by: Product Safety Department (US) +1 866-430-2775 Further information for the safety data sheet : [email protected] 1.4 Emergency telephone number Emergency telephone number: +44 (0)208 762 8322 For additional emergency telephone numbers see section 16 of the Safety Data Sheet. 2. Hazards identification 2.1 Classification of the substance or mixture Classification (67/548/EEC, 1999/45/EC) Irritant R43: May cause sensitization by skin contact. Dangerous for the environment R51/53: Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 2.2 Label elements
- 2. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 2 / 15 SDS Number: 400000004589 Labelling (REGULATION (EC) No 1272/2008) Labelling according to EC Directives () Hazard pictograms : Irritant Dangerous for the environment R-phrase(s) : R43 May cause sensitization by skin contact. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. S-phrase(s) : S24 Avoid contact with skin. S37 Wear suitable gloves. S57 Use appropriate container to avoid environmental contamination. S61 Avoid release to the environment. Refer to special instructions/ Safety data sheets. Hazardous components which must be listed on the label: 149877-41-8 Bifenazate 2.3 Other hazards No information available. 3. Composition/information on ingredients 3.2 Mixtures Chemical nature : Acaricide Hazardous components Chemical Name CAS-No. EC-No. Registration number Classification (67/548/EEC) Classification (REGULATION (EC) No 1272/2008) Concentration [%] Bifenazate 149877-41-8 442-820-5 Xi-N; R43-R50/53 Skin Sens. 1; H317 STOT RE 2; H373 Aquatic Acute 1; H400 43.46 propane-1,2-diol 57-55-6 200-338-0 < 10
- 3. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 3 / 15 SDS Number: 400000004589 For the full text of the R-phrases mentioned in this Section, see Section 16. For the full text of the H-Statements mentioned in this Section, see Section 16. 4. First aid measures 4.1 Description of first aid measures If inhaled : Remove to fresh air. Obtain medical attention. In case of skin contact : Remove contaminated clothing and shoes. Wash off with warm water and soap. If symptoms persist, call a physician. In case of eye contact : Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. If symptoms persist, call a physician. If swallowed : Do NOT induce vomiting. Rinse mouth with water. Obtain medical attention. 4.2 Most important symptoms and effects, both acute and delayed Symptoms : sensitising effects Risks : sensitising effects 4.3 Indication of any immediate medical attention and special treatment needed Treatment : The first aid procedure should be established in consultation with the doctor responsible for industrial medicine. 5. Fire-fighting measures 5.1 Extinguishing media Suitable extinguishing media : Extinguishing media - large fires Alcohol-resistant foam (on small fires) Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing media : Water spray jet 5.2 Special hazards arising from the substance or mixture Specific hazards during fire : Burning produces irritant fumes.
- 4. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 4 / 15 SDS Number: 400000004589 fighting Exposure to decomposition products may be a hazard to health. 5.3 Advice for firefighters Special protective equipment for fire-fighters : In the event of fire, wear self-contained breathing apparatus. Use personal protective equipment. Further information : Prevent fire extinguishing water from contaminating surface water or the ground water system. 6. Accidental release measures 6.1 Personal precautions, protective equipment and emergency procedures Personal precautions : Wear suitable protective equipment. Avoid contact with skin and eyes. 6.2 Environmental precautions Environmental precautions : Should not be released into the environment. Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration. 6.3 Methods and materials for containment and cleaning up Methods for cleaning up : Dam up. Soak up with inert absorbent material (e.g. sand, silica gel, acid binder, universal binder, sawdust). Pick up and transfer to properly labelled containers. Large spills should be collected mechanically (remove by pumping) for disposal. 6.4 Reference to other sections Refer to protective measures listed in sections 7 and 8. 7. Handling and storage 7.1 Precautions for safe handling Advice on safe handling : Handle in accordance with good industrial hygiene and safety practice. Avoid contact with skin and eyes. Avoid inhalation of vapour or mist. Use with adequate ventilation. Wash thoroughly after handling. 7.2 Conditions for safe storage, including any incompatibilities Requirements for storage : Keep in a dry, cool place.
- 5. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 5 / 15 SDS Number: 400000004589 areas and containers Other data : Stable under recommended storage conditions. 7.3 Specific end uses Specific use(s) : Acaricide 8. Exposure controls/personal protection 8.1 Control parameters Components CAS-No. Value Control parameters Update Basis propane-1,2-diol 57-55-6 TWA 150 ppm 474 mg/m3 2005-04-06 GB EH40 TWA 10 mg/m3 2005-04-06 GB EH40 8.2 Exposure controls Personal protective equipment Respiratory protection : When workers are facing concentrations above the exposure limit they must use appropriate certified respirators. Hand protection : Chemical resistant protective gloves Eye protection : Safety glasses with side-shields Skin and body protection : Long sleeved clothing Lab coat Environmental exposure controls General advice : Should not be released into the environment. Do not flush into surface water or sanitary sewer system. Avoid subsoil penetration.
- 6. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 6 / 15 SDS Number: 400000004589 9. Physical and chemical properties 9.1 Information on basic physical and chemical properties Appearance : liquid Colour : off-white, to, tan Odour : characteristic Odour Threshold : No information available. Flash point : >104 °C Ignition temperature : No information available. Upper explosion limit : no data available Flammability (solid, gas) : No information available. Autoignition temperature : No information available. pH : 7.0 Boiling point/boiling range : Note: no data available Vapour pressure : similar to water Density : 1.104 g/cm3 Water solubility : dispersible Partition coefficient: n- octanol/water : No information available. Solubility in other solvents : No information available. Viscosity, dynamic : 550 mPa.s at 25 °C Relative vapour density : No information available. Evaporation rate : No information available. 9.2 Other information Lower explosion limit : no data available
- 7. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 7 / 15 SDS Number: 400000004589 10. Stability and reactivity 10.1 Reactivity No dangerous reaction known under conditions of normal use. 10.2 Chemical stability Stable under normal conditions. 10.3 Possibility of hazardous reactions Hazardous reactions : Hazardous polymerisation does not occur. 10.4 Conditions to avoid Conditions to avoid : Extremes of temperature and direct sunlight. 10.5 Incompatible materials Materials to avoid : Oxidizing agents Strong acids and strong bases 10.6 Hazardous decomposition products Hazardous decomposition products : Carbon oxides 11. Toxicological information 11.1 Information on toxicological effects Acute toxicity Acute oral toxicity : LD50: > 5,000 mg/kg Species: rat : LD50: > 2,000 mg/kg Species: rat Acute oral toxicity Bifenazate : LD50: > 5,000 mg/kg Species: rat Method: OECD Test Guideline 401 propane-1,2-diol : LD50: 20,000 mg/kg Species: rat LD50: 18,500 mg/kg Species: rabbit
- 8. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 8 / 15 SDS Number: 400000004589 Acute inhalation toxicity : LC50: > 1.8 mg/l Exposure time: 4 h Species: rat Acute dermal toxicity : LD50: > 5,000 mg/kg Species: rabbit Acute dermal toxicity Bifenazate : LD50: > 5,000 mg/kg Species: rat Method: OECD Test Guideline 402 propane-1,2-diol : LD50: 20,800 mg/kg Species: rabbit Skin corrosion/irritation Skin irritation : Species: rabbit Result: No skin irritation Skin irritation Bifenazate : Species: rabbit Result: No skin irritation Method: OECD Test Guideline 404 Exposure time: 4 h Serious eye damage/eye irritation Eye irritation : Species: rabbit Result: No eye irritation Eye irritation Bifenazate : Species: rabbit Result: No eye irritation Method: OECD Test Guideline 405 Exposure time: 48 h Respiratory or skin sensitization Sensitisation : Species: guinea pig Classification: May cause sensitization by skin contact. Sensitisation Bifenazate : Maximisation Test Species: guinea pig Classification: May cause sensitization by skin contact.
- 9. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 9 / 15 SDS Number: 400000004589 Method: OECD Test Guideline 406 Germ cell mutagenicity Bifenazate : Ames test Result: negative In Vitro mammalian Cell Gene Mutation Test Result: negative Chromosome aberration test in vitro Result: negative Genotoxicity in vivo Bifenazate : Micronucleus test Species: mouse Result: negative Mutagenicity Assessment Remarks : negative Carcinogenicity Assessment Remarks : negative Reproductive toxicity Assessment Remarks : negative Target Organ Systemic Toxicant - Repeated exposure Bifenazate : Exposure routes: Oral Target Organs: Blood Remarks: Causes damage to organs through prolonged or repeated exposure. Toxicology Assessment 12. Ecological information 12.1 Toxicity Toxicity to fish : LC50: 1.4 mg/l Exposure time: 96 h
- 10. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 10 / 15 SDS Number: 400000004589 Species: Oncorhynchus mykiss (rainbow trout) Toxicity to fish Bifenazate : LC50: 0.76 mg/l Exposure time: 96 h Species: Oncorhynchus mykiss (rainbow trout) flow-through test Analytical monitoring: yes LC50: 0.58 mg/l Exposure time: 96 h Species: Lepomis machrochirus (Bluegill) flow-through test Analytical monitoring: yes LC50: 0.42 mg/l Exposure time: 96 h Species: Cyprinodon variegatus (sheepshead minnow) flow-through test Analytical monitoring: yes Toxicity to daphnia and other aquatic invertebrates. : EC50: 1.4 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) Toxicity to daphnia and other aquatic invertebrates. Bifenazate : LC50: 0.5 mg/l Exposure time: 48 h Species: Daphnia magna (Water flea) flow-through test Analytical monitoring: yes Toxicity to algae : EC50: 1.3 mg/l Exposure time: 72 h Species: Algae Toxicity to algae Bifenazate : EbC50: 0.89 mg/l Exposure time: 96 h Species: Raphidocelis subcapitata (freshwater green alga) static test Analytical monitoring: yes Method: OECD Test Guideline 201 ErC50: > 2.02 mg/l
- 11. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 11 / 15 SDS Number: 400000004589 Exposure time: 96 h Species: Raphidocelis subcapitata (freshwater green alga) static test Analytical monitoring: yes Method: OECD Test Guideline 201 ErC50: 0.36 mg/l Exposure time: 96 h Species: Skeletonema costatum (marine diatom) static test Analytical monitoring: yes Method: OECD Test Guideline 201 ErC50: 1.4 mg/l Exposure time: 96 h Species: Algae static test Analytical monitoring: yes Method: OECD Test Guideline 201 ErC50: > 4.48 mg/l Exposure time: 96 h Species: Algae static test Analytical monitoring: yes Method: OECD Test Guideline 201 12.2 Persistence and degradability Biodegradability : Remarks: no data available 12.3 Bioaccumulative potential Bioaccumulation Bifenazate : Bioconcentration factor (BCF): 83 Method: estimated 12.4 Mobility in soil Mobility : Remarks: no data available 12.5 Results of PBT and vPvB assessment This mixture contains no substance considered to be persistent, bioaccumulating nor toxic (PBT). 12.6 Other adverse effects
- 12. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 12 / 15 SDS Number: 400000004589 13. Disposal considerations 13.1 Waste treatment methods Product : In accordance with local and national regulations. Do not dispose of waste into sewer. 14. Transport information ADR UN number : 3082 UN proper shipping name : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bifenazate) Transport hazard class(es) : 9 Packing group : III Classification Code : M6 Hazard identification No : 90 Labels : 9 Tunnel restriction code : (E) Environmentally hazardous : yes IATA UN number : 3082 Description of the goods : Environmentally hazardous substance, liquid, n.o.s. (Bifenazate) Class : 9 Packing group : III Labels : 9 Packing instruction (cargo aircraft) : 914 Environmentally hazardous : yes Packing instruction (passenger aircraft) : 914 Packing instruction (passenger aircraft) : Y914 IMDG
- 13. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 13 / 15 SDS Number: 400000004589 UN number : 3082 Description of the goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bifenazate) Class : 9 Packing group : III Labels : 9 EmS Number 1 : F-A EmS Number 2 : S-F Marine pollutant : yes Bifenazate RID UN number : 3082 Description of the goods : ENVIRONMENTALLY HAZARDOUS SUBSTANCE, LIQUID, N.O.S. (Bifenazate) Transport hazard class(es) : 9 Packing group : III Classification Code : M6 Hazard identification No : 90 Labels : 9 Environmentally hazardous : yes 15. Regulatory information 15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture Candidate List of Substances of Very High Concern for Authorisation : This product does not contain substances of very high concern (Regulation (EC) No 1907/2006 (REACH), Article 57). Major Accident Hazard Legislation : 96/82/EC Update: 2003 Dangerous for the environment 9b Quantity 1: 200 t Quantity 2: 500 t Water contaminating class (Germany) : WGK 3 highly water endangering Notification status
- 14. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 14 / 15 SDS Number: 400000004589 US.TSCA : Not On TSCA Inventory DSL : This product contains the following components that are not on the Canadian DSL nor NDSL lists. AICS : Not in compliance with the inventory NZIoC : Not in compliance with the inventory ENCS : Not in compliance with the inventory KECI : Not in compliance with the inventory PICCS : Not in compliance with the inventory IECSC : Not in compliance with the inventory CH INV : The formulation contains substances listed on the Swiss Inventory 15.2 Chemical Safety Assessment 16. Other information Full text of R-phrases referred to under sections 2 and 3 R43 May cause sensitization by skin contact. R50/53 Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. Full text of H-Statements referred to under sections 2 and 3. H317 May cause an allergic skin reaction. H373 May cause damage to organs through prolonged or repeated exposure if swallowed. H400 Very toxic to aquatic life. Carechem24 International Worldwide Coverage - Chemtura Corporation Emergency Phone Number Europe: All European Countries +44 (0) 1235 239 670 Asia Pacific: East / South East Asia – Regional Number +65 3158 1074 Australia +61 2801 44558 New Zealand +64 9929 1483 China Taiwan +86 10 5100 3039 Japan +81 345 789 341 Indonesia 00780 3011 0293 Malaysia +60 3 6207 4347 Thailand 001800 1 2066 6751 Korea +65 3158 1285
- 15. SAFETY DATA SHEET according to Regulation (EC) No. 1907/2006 Enviromite 480SC Version 1.7 Revision Date 15.06.2011 Print Date 15.06.2011 SAP 6.0 15 / 15 SDS Number: 400000004589 Vietnam +65 3158 1255 India +65 3158 1198 Pakistan +65 3158 1329 Philippines +65 31581203 Sri Lanka +65 3158 1195 Bangladesh +65 3158 1200 Middle East / Africa: Arabic speaking countries +44 (0) 1235 239 671 All other countries +44 (0) 1235 239 670 America United States / Canada 001866 928 0789 Latin America: Brazil +55 113 711 9144 All other countries +44 (0) 1235 239 670 Mexico +52 555 004 87 63 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text.