Chapter 2 of the EIGRP instructor materials covers fundamental concepts, configuration modes, and operational details of the Enhanced Interior Gateway Routing Protocol (EIGRP). It discusses how EIGRP forms neighbor relationships, handles route metrics, and provides two configuration modes: classic and named mode, with emphasis on features like load balancing, rapid convergence, and security through authentication. Moreover, it elaborates on key terminologies, topology tables, and techniques for verifying EIGRP operation in network environments.