Queue is a first-in, first-out (FIFO) data structure. It can be implemented using arrays or linked lists. The key operations are enqueue to add an item to the rear and dequeue to remove an item from the front. When using an array to implement a queue, a front and rear pointer track the first and last elements. Items are added by incrementing rear and removed by incrementing front. A circular queue solves the problem of overflow by treating the array as a circular structure.