2. • In 20th
century, many advancements in packaging
technology appeared i.e.
1. Intelligent or smart packaging {IOSP; time‐
temperature indicators (TTIs), gas indicators,
microwave doneness indicators, radiofrequency
identification (RFID)}, and
2. Active packaging (AP; such as oxygen scavengers,
moisture absorbers, and antimicrobials).
• These innovations further improved food quality, food
safety, and shelf life.
‐
3. Active Packaging (AP)
• AP can effectively improve food quality
(including safety) and extend shelf life by
‐
positively affecting the headspace of a
packaged product and the product itself (by
releasing an antimicrobial or antioxidant
compound).
8. Iron-based Oxygen Absorber
• Initially the iron-based scavengers are Ferrous
oxide (FeO).
• When FeO is exposed to environmental
moisture, it becomes activated & absorb Oxygen.
• It converts into Ferric Oxide (Fe2O3).
• LD50 for these iron based O2 absorbers = 16g/kg
body weight.
• A man of 70kg would be negatively impacted by
consumption of almost 448 sachets of 2.2g O2
absorbents.
15. CO2 Scavenger
• High amounts of CO2 are required for Meat
and its products.
• For Fruits and Veges, low level of CO2 is
required, as high level will trigger Anaerobic
glycolysis.
• Most Widely used CO2 scavenger is Calcium
Hydroxide.
• Ca(OH)2 + CO2 = CaCO3 + H2O
• Used for freshly ground coffee.
30. Zein: Major storage protein in corn that is soluble in alcoholic solution.
It is a great candidate as an edible film-forming agent since it has excellent film-forming
ability, good solubility in ethanol, and compatibility with many natural active agents.
Zein finds uses as a water-protective coating material for nuts and confectionery products.
LDPE: Low Density Polyethylene
34. Limitation in Active Packaging
• But, this packaging technique cannot provide
visual information indicative of the shelf life,
‐
safety, or quality of food.
35. • Food packaging innovations have led to the
development of intelligent packaging, which
can convey detailed information about the
condition of a packaged food or its
environment throughout a logistical chain, as
well as provide early warning to the consumer
from the food manufacturer.
36. • Currently available intelligent packaging
technologies can accomplish diverse functions
such as monitoring, identifying, processing,
recording, tracing, and communicating
information.
• This information promote decision making
‐
efficiency, extend shelf life, and communicate
‐
information about the state and quality of the
product through the supply chain.
37. Authorities for Food Packaging
• All food packaging materials must be
rigorously tested by food safety agencies such
as the U.S. Food and Drug Administration
(FDA), the Brazil National Health Surveillance
Agency, and the European Commission (EC),
which are responsible for ensuring the safety
of food packaging materials and additives
before they can be used in food.
39. Smart packaging never acts on food, it just monitor the condition of food and
convey information regarding it.
43. Types of IP
1. Quality Indicator
• Freshness Indicator,
• Ripening Sensor,
• Sensor-QTM (Microbial Growth).
2. Time Temperature Indicator
• VITSAB (Visual Indicator Tag System)
• Temp-Time
• Monitor Mark.
3. Gas Concentration Indicator
44. 1. Quality Indicator
Indicates the acceptability of product quality
during Storage, Transportation, Retailing and
Consumer’s place.
Indicates product’s spoilage or absence of
freshness due to inappropriate temperature
during supply chain or storage or leakage of
packaging.
Gives visible color change as indicator of CO2 ,
Amines, O2, Ammonia or Hydrogen Sulfide.
45. Freshness Indicator
• Kimchi is fermented product, made with
cucumber, cabbage or radish.
• Kimchi has a normal pH of 4.2 and titrable
acidity range from 0.6 to 0.8
• If proper storage and transportation
conditions are not followed then the product
is deteriorated due to excessive Organic Acid
production and loss of texture.
48. • These sensors were initially developed for
fruits like Pear, as it is quite difficult to assess
the ripening status of Pear.
51. TIME-Temperature Indicator (TTI)
• Use for Temperature sensitive products.
• Indicates the product’s exposure to temperature
with time.
• Types of TTI
a. Partial History Indicator: Does not respond until
some pre-determined threshold temperature has
been exceeded.
b. Full History Indicator: Respond continuously to
each temperature.
Standard Guide for Selection of Time-Temperature
Indicator was introduced in 2003.
56. The color change and the bar codes are monitored using
specially programmed, hand-held microcomputer with an optical
wand, which records the decrease in reflection as the indication
band darkens.
63. Oxygen Indicator DYE
• 2 different absorption based opto chemical indicators for
‐ ‐
oxygen, which consist of leuco dyes
1. leuco indigo (LI)
2. leuco thioindigo (LTI) dye
• Incorporated into two kinds of polymer matrices, poly(styrene‐
co acrylonitrile) (PSAN, with 30% acrylonitrile) and polymer
‐
hydrogel D4 (a linear polyurethane).
• LI D4 (leuco indigo incorporated into a hydrogel polymer)
‐
induces an irreversible color change (from pale yellow to deep
blue) that indicates the presence of air (oxygen) within a few
minutes, which is important for detecting leaks in food packed
under a modified atmosphere.
• However, the LTI PSAN indicator (leuco thioindigo incorporated
‐
into PSAN) required several hours to gradually change its color
from yellow to red after exposure to air.
64. Advantages of O2 Indicators
• Cost effective means of visually detecting and
‐
monitoring the seal status and quality
deterioration of packaged foods, including fish
and meat
65. Carbon dioxide indicator
• Respond to the presence of carbon dioxide via
a color change from red to yellow.
• CO2 indicators also measure the degree of
fermentation in kimchi products during
storage and distribution and displaying the
concentration of carbon dioxide inside
modified atmosphere packaging (MAP)
67. 1. Thermo-chromic Inks
When a product is exposed to a particular temperature, the color of
these inks changes.
It appear like *TOO HOT*, *Drink Now*.
Thermo-chromic inks or dyes are temperature sensitive compounds
that temporarily change color with exposure to heat. They come in
two forms, liquid crystals and leuco dyes. Leuco dyes are easier to
work with and allow for a greater range of applications.
72. Sustainable or Green Packaging (SOGP)
• Environmentally friendly.
• Aim to minimize the environmental impact of
the entire product packaging chain and
‐
improve the environmental sustainability of
food packaging systems
73. SOGP can be achieved at 3 Levels
1. Raw materials level, the use of recycled
materials.
2. Production level, SOGP utilizes lighter and
thinner packaging that is produced using
relatively energy efficient processes.
‐
3. Waste management level, reuse or recycling of
food packaging that is biodegradable and/or
compostable can contribute to alleviating the
problem of municipal solid waste.
74. • The trend of bio-plastic development and application
in food packaging has increased.
• According to the European Bio-plastics Organization,
bioplastics are based on renewable resources or
plastics that are biodegradable and/or compostable.
• But, not all biopolymers are biodegradable.
• Polyethylene (“green PE”) and polyethylene
‐
terephthalate (“bio PET”) are obtained from
‐
renewable resources and are chemically identical to
conventional polymers
• Green PE and Bio-PET are non-biodegradable.
75. • A wide range of biodegradable biopolymers
have been used in food packaging, including
polyhydroxyalkanoates (PHAs), polylactic acid
(PLA), zein, soy protein isolate, starches,
cellulose, gluten, whey protein isolate, and
chitosan.
• Chitosan is a natural polymer, nontoxic, edible,
and biodegradable derived by deacetylation of
chitin which is the second most abundant
biopolymer in nature after cellulose
77. limitations in application of bioplastics in food
packaging materials
1. Their high cost compared to conventional
plastics,
2. brittleness, delicate in nature
3. thermal instability,
4. low melt strength,
5. difficult heat seal-ability,
6. high water vapor permeability,
7. high oxygen permeability,
8. bad process-ability, and
9. poor impact resistance
78. Modifications
• To improve the properties of bioplastics
(especially their barrier capacities toward
gases and water), different techniques have
been presented such as
• coating bio-based films, incorporation of
nanoparticles or biopolymer cellulose.
79. Example
• Thin (25 nm) and highly uniform Al2O3 coating
can significantly improve the oxygen and
water vapour barrier performance of several
materials (PLA coated board, PLA film, nano
‐ ‐
fibrillated cellulose film, PHB) by using the
atomic layer deposition (ALD) technique
81. • Incorporation of nano-magnesium oxide and
clove essential oil into a chitosan matrix
increased its tensile strength (TS), elongation
limit, and water barrier performance.
• The lipid nature of essential oils can decrease
water vapor permeability in hydrophilic
materials and can also improve the structural,
mechanical, and optical properties of
packaging films.
82. Examples
• The biodegradable packaging films developed and
tested on tomato fruit in Finland for preservation
objectives resulted in extended shelf life.
• In Malaysia, the use of gum arabic as edible coating
film for extending the shelf life and postharvest
quality of tomato.
• Starch edible coatings derived from Colombian native
potatoes were applied on Andean blueberry (a wild
fruit native to South America) resulting in reduced
respiration rate of ~27%.
83. • In Ethiopia, the film produced from pectin and
chitosan extract and tested on tomato
resulted in extended shelf life (15-17 days)
compared to the control (10 days).
90. Improvements in SOGP
• Using carboxylic acids and calcium ions as crosslinking
agents can improve the physiochemical, thermal, and
mechanical properties of most biopolymers such as
alginate, pectin, whey proteins, chitosan, starch, and
gelatin.
• From environmental, cost, and health perspectives, the
crosslinking approach is a more cost effective and efficient
‐
method of improving the permeability of film forming
‐
biopolymers compared to nanotechnology, especially for
naturally occurring crosslinking agents, such as some
nanoparticles, which can induce intracellular damage,
pulmonary inflammation, and vascular disease when they
migrate into food
91. • Packaging reduction i.e.
• Avoid excessive packaging by reducing the
amount of packaging materials used without
compromising the appearance of packaged
products.
• Avoiding over-packaging can improve
environmental sustainability and reduce the
cost of product processing, which can lower
the price of the product.
• reduce the weight and thickness of packaging
without affecting product shelf life standards.
‐
Editor's Notes
#4:AP scavenge undesired gases i.e. Oxygen, Moisture. and release the desired compounds such as Antimicrobial or antioxidant agents.
#21:Kaolin = Chemical compound composed of Aluminum hydroxide and Silicone oxide.
Kaolinite
#24:Silica was previously used, now Ethylene Vinyl Alcohol is used
#31:Insulating Material: Fiberglass, cellulose, Polystyrene.
Microwave susceptors are incorporated in paper packaging to absorb microwaves and warm the product.
#32:Water and quick lime reaction is an exothermic reaction
#55:The indication band contains diacetylene monomers (R – C Ξ C – C Ξ C – R), which appear colourless because they absorb light only in UV portion of the spectrum.
#79:Polyhydroxybutyrate (PHB)
PLA= Polylactic Acid
ALD= a vapor phase technique used to deposit thin films onto a substrate.
#80:Nano-cellulose fibers are treated with sulphuric acid or HCl, followed by Sonication.
Sonication is the process of applying sound energy to agitate particles or discontinuous fibers in a liquid.